Bis(N-isopropyl-N-methyl­dithio­carbamato-κ(2) S,S′)(1,10-phenanthroline-κ(2) N,N′)zinc

The Zn(II) atom in the title compound, [Zn(C(5)H(10)NS(2))(2)(C(12)H(8)N(2))], exists in a distorted cis-octa­hedral N(2)S(4) donor set defined by two chelating dithio­carbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing i...

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Detalles Bibliográficos
Autores principales: Wahab, Nor Asiken Abdul, Baba, Ibrahim, Mohamed Tahir, Mohamed Ibrahim, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089284/
https://www.ncbi.nlm.nih.gov/pubmed/21754288
http://dx.doi.org/10.1107/S1600536811012499
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author Wahab, Nor Asiken Abdul
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
author_facet Wahab, Nor Asiken Abdul
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
author_sort Wahab, Nor Asiken Abdul
collection PubMed
description The Zn(II) atom in the title compound, [Zn(C(5)H(10)NS(2))(2)(C(12)H(8)N(2))], exists in a distorted cis-octa­hedral N(2)S(4) donor set defined by two chelating dithio­carbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak C—H⋯S, C—H⋯π(ZnS(2)C) and π–π [ring centroid distance between centrosymmetrically related pyridyl rings = 3.5955 (13) Å] inter­actions.
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spelling pubmed-30892842011-07-13 Bis(N-isopropyl-N-methyl­dithio­carbamato-κ(2) S,S′)(1,10-phenanthroline-κ(2) N,N′)zinc Wahab, Nor Asiken Abdul Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn(II) atom in the title compound, [Zn(C(5)H(10)NS(2))(2)(C(12)H(8)N(2))], exists in a distorted cis-octa­hedral N(2)S(4) donor set defined by two chelating dithio­carbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak C—H⋯S, C—H⋯π(ZnS(2)C) and π–π [ring centroid distance between centrosymmetrically related pyridyl rings = 3.5955 (13) Å] inter­actions. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089284/ /pubmed/21754288 http://dx.doi.org/10.1107/S1600536811012499 Text en © Wahab et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wahab, Nor Asiken Abdul
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
Bis(N-isopropyl-N-methyl­dithio­carbamato-κ(2) S,S′)(1,10-phenanthroline-κ(2) N,N′)zinc
title Bis(N-isopropyl-N-methyl­dithio­carbamato-κ(2) S,S′)(1,10-phenanthroline-κ(2) N,N′)zinc
title_full Bis(N-isopropyl-N-methyl­dithio­carbamato-κ(2) S,S′)(1,10-phenanthroline-κ(2) N,N′)zinc
title_fullStr Bis(N-isopropyl-N-methyl­dithio­carbamato-κ(2) S,S′)(1,10-phenanthroline-κ(2) N,N′)zinc
title_full_unstemmed Bis(N-isopropyl-N-methyl­dithio­carbamato-κ(2) S,S′)(1,10-phenanthroline-κ(2) N,N′)zinc
title_short Bis(N-isopropyl-N-methyl­dithio­carbamato-κ(2) S,S′)(1,10-phenanthroline-κ(2) N,N′)zinc
title_sort bis(n-isopropyl-n-methyl­dithio­carbamato-κ(2) s,s′)(1,10-phenanthroline-κ(2) n,n′)zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089284/
https://www.ncbi.nlm.nih.gov/pubmed/21754288
http://dx.doi.org/10.1107/S1600536811012499
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