rac-12,14-Dicyclo­propyl-5,8,13,18,21-penta­oxapenta­cyclo­[13.8.0.0(2,11).0(4,9).0(17,22)]tricosa-1(15),2(11),3,9(10),16,22(23)-hexa­ene

The mol­ecule of the title compound, C(24)H(24)O(5), has crystallographic twofold symmetry, with the central O atom lying on the rotation axis. The dihedral angle between the best planes of the benzene rings fused to the oxepine fragment is 38.5 (1)°. The dioxine ring adopts a twist form with the et...

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Detalles Bibliográficos
Autores principales: Tafeenko, Viktor A., Aslanov, Leonid A., Puretskiy, Nikolay A., Fedotov, Aleksander N., Mochalov, Sergei S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089285/
https://www.ncbi.nlm.nih.gov/pubmed/21754483
http://dx.doi.org/10.1107/S1600536811013961
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author Tafeenko, Viktor A.
Aslanov, Leonid A.
Puretskiy, Nikolay A.
Fedotov, Aleksander N.
Mochalov, Sergei S.
author_facet Tafeenko, Viktor A.
Aslanov, Leonid A.
Puretskiy, Nikolay A.
Fedotov, Aleksander N.
Mochalov, Sergei S.
author_sort Tafeenko, Viktor A.
collection PubMed
description The mol­ecule of the title compound, C(24)H(24)O(5), has crystallographic twofold symmetry, with the central O atom lying on the rotation axis. The dihedral angle between the best planes of the benzene rings fused to the oxepine fragment is 38.5 (1)°. The dioxine ring adopts a twist form with the ethyl­ene group C atoms deviating by 0.472 (5) and −0.248 (6) Å from the plane defined by the remaining ring atoms.
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spelling pubmed-30892852011-07-13 rac-12,14-Dicyclo­propyl-5,8,13,18,21-penta­oxapenta­cyclo­[13.8.0.0(2,11).0(4,9).0(17,22)]tricosa-1(15),2(11),3,9(10),16,22(23)-hexa­ene Tafeenko, Viktor A. Aslanov, Leonid A. Puretskiy, Nikolay A. Fedotov, Aleksander N. Mochalov, Sergei S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(24)H(24)O(5), has crystallographic twofold symmetry, with the central O atom lying on the rotation axis. The dihedral angle between the best planes of the benzene rings fused to the oxepine fragment is 38.5 (1)°. The dioxine ring adopts a twist form with the ethyl­ene group C atoms deviating by 0.472 (5) and −0.248 (6) Å from the plane defined by the remaining ring atoms. International Union of Crystallography 2011-04-22 /pmc/articles/PMC3089285/ /pubmed/21754483 http://dx.doi.org/10.1107/S1600536811013961 Text en © Tafeenko et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tafeenko, Viktor A.
Aslanov, Leonid A.
Puretskiy, Nikolay A.
Fedotov, Aleksander N.
Mochalov, Sergei S.
rac-12,14-Dicyclo­propyl-5,8,13,18,21-penta­oxapenta­cyclo­[13.8.0.0(2,11).0(4,9).0(17,22)]tricosa-1(15),2(11),3,9(10),16,22(23)-hexa­ene
title rac-12,14-Dicyclo­propyl-5,8,13,18,21-penta­oxapenta­cyclo­[13.8.0.0(2,11).0(4,9).0(17,22)]tricosa-1(15),2(11),3,9(10),16,22(23)-hexa­ene
title_full rac-12,14-Dicyclo­propyl-5,8,13,18,21-penta­oxapenta­cyclo­[13.8.0.0(2,11).0(4,9).0(17,22)]tricosa-1(15),2(11),3,9(10),16,22(23)-hexa­ene
title_fullStr rac-12,14-Dicyclo­propyl-5,8,13,18,21-penta­oxapenta­cyclo­[13.8.0.0(2,11).0(4,9).0(17,22)]tricosa-1(15),2(11),3,9(10),16,22(23)-hexa­ene
title_full_unstemmed rac-12,14-Dicyclo­propyl-5,8,13,18,21-penta­oxapenta­cyclo­[13.8.0.0(2,11).0(4,9).0(17,22)]tricosa-1(15),2(11),3,9(10),16,22(23)-hexa­ene
title_short rac-12,14-Dicyclo­propyl-5,8,13,18,21-penta­oxapenta­cyclo­[13.8.0.0(2,11).0(4,9).0(17,22)]tricosa-1(15),2(11),3,9(10),16,22(23)-hexa­ene
title_sort rac-12,14-dicyclo­propyl-5,8,13,18,21-penta­oxapenta­cyclo­[13.8.0.0(2,11).0(4,9).0(17,22)]tricosa-1(15),2(11),3,9(10),16,22(23)-hexa­ene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089285/
https://www.ncbi.nlm.nih.gov/pubmed/21754483
http://dx.doi.org/10.1107/S1600536811013961
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