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catena-Poly[[aqua­(benzoato-κ(2) O,O′)(benzoic acid-κO)calcium]-μ(3)-benzoato-κ(4) O:O,O′:O′]

In title compound, [Ca(C(7)H(5)O(2))(2)(C(7)H(6)O(2))(H(2)O)](n), the eightfold-coordinated Ca(II) ion is bonded to four carboxyl­ate O atoms from two benzoate ions, an O atom from benzoic acid and a water O atom. One of the carboxyl­ate groups bridges adjacent Ca(2+) ions, forming a polymeric ribbo...

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Detalles Bibliográficos
Autores principales: Azizov, Olimjon, Kadirova, Zukhra, Azizov, Tohir, Tolipov, Samat, Ibragimov, Bakhtiyar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089294/
https://www.ncbi.nlm.nih.gov/pubmed/21754317
http://dx.doi.org/10.1107/S1600536811013493
Descripción
Sumario:In title compound, [Ca(C(7)H(5)O(2))(2)(C(7)H(6)O(2))(H(2)O)](n), the eightfold-coordinated Ca(II) ion is bonded to four carboxyl­ate O atoms from two benzoate ions, an O atom from benzoic acid and a water O atom. One of the carboxyl­ate groups bridges adjacent Ca(2+) ions, forming a polymeric ribbon structure parallel to [010]. In the crystal, the benzoate anions and water mol­ecule inter­act by way of inter- and intra­molecular O—H⋯O hydrogen bonds.