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2-(N-Phenyl­methane­sulfonamido)­ethyl 1H-pyrrole-2-carboxyl­ate

In the title compound, C(14)H(16)N(2)O(4)S, the eth­oxy­carbonyl group is nearly planar, with an r.m.s. deviation of 0.0067 Å, and is almost coplanar with the pyrrole ring [dihedral angle = 5.81 (15)°], whereas it is inclined at a dihedral angle of 61.90 (13)° to the phenyl ring. The dihedral angle...

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Autores principales: Khan, Salman Tariq, Yu, Peng, Nelofar, Aisha, Ahmed, Zaheer, Chantrapromma, Suchada
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089296/
https://www.ncbi.nlm.nih.gov/pubmed/21754438
http://dx.doi.org/10.1107/S160053681101261X
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author Khan, Salman Tariq
Yu, Peng
Nelofar, Aisha
Ahmed, Zaheer
Chantrapromma, Suchada
author_facet Khan, Salman Tariq
Yu, Peng
Nelofar, Aisha
Ahmed, Zaheer
Chantrapromma, Suchada
author_sort Khan, Salman Tariq
collection PubMed
description In the title compound, C(14)H(16)N(2)O(4)S, the eth­oxy­carbonyl group is nearly planar, with an r.m.s. deviation of 0.0067 Å, and is almost coplanar with the pyrrole ring [dihedral angle = 5.81 (15)°], whereas it is inclined at a dihedral angle of 61.90 (13)° to the phenyl ring. The dihedral angle between the pyrrole and phenyl rings is 56.15 (13)°. In the crystal, centrosymmetrically related mol­ecules are linked into dimers by pairs of N—H⋯O hydrogen bonds, forming rings of R (2) (2)(10) graph-set motif. The dimers are further connected by weak inter­molecular C—H⋯O hydrogen bonds and C—H⋯π inter­actions, forming layers parallel to the bc plane.
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spelling pubmed-30892962011-07-13 2-(N-Phenyl­methane­sulfonamido)­ethyl 1H-pyrrole-2-carboxyl­ate Khan, Salman Tariq Yu, Peng Nelofar, Aisha Ahmed, Zaheer Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(16)N(2)O(4)S, the eth­oxy­carbonyl group is nearly planar, with an r.m.s. deviation of 0.0067 Å, and is almost coplanar with the pyrrole ring [dihedral angle = 5.81 (15)°], whereas it is inclined at a dihedral angle of 61.90 (13)° to the phenyl ring. The dihedral angle between the pyrrole and phenyl rings is 56.15 (13)°. In the crystal, centrosymmetrically related mol­ecules are linked into dimers by pairs of N—H⋯O hydrogen bonds, forming rings of R (2) (2)(10) graph-set motif. The dimers are further connected by weak inter­molecular C—H⋯O hydrogen bonds and C—H⋯π inter­actions, forming layers parallel to the bc plane. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089296/ /pubmed/21754438 http://dx.doi.org/10.1107/S160053681101261X Text en © Khan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Khan, Salman Tariq
Yu, Peng
Nelofar, Aisha
Ahmed, Zaheer
Chantrapromma, Suchada
2-(N-Phenyl­methane­sulfonamido)­ethyl 1H-pyrrole-2-carboxyl­ate
title 2-(N-Phenyl­methane­sulfonamido)­ethyl 1H-pyrrole-2-carboxyl­ate
title_full 2-(N-Phenyl­methane­sulfonamido)­ethyl 1H-pyrrole-2-carboxyl­ate
title_fullStr 2-(N-Phenyl­methane­sulfonamido)­ethyl 1H-pyrrole-2-carboxyl­ate
title_full_unstemmed 2-(N-Phenyl­methane­sulfonamido)­ethyl 1H-pyrrole-2-carboxyl­ate
title_short 2-(N-Phenyl­methane­sulfonamido)­ethyl 1H-pyrrole-2-carboxyl­ate
title_sort 2-(n-phenyl­methane­sulfonamido)­ethyl 1h-pyrrole-2-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089296/
https://www.ncbi.nlm.nih.gov/pubmed/21754438
http://dx.doi.org/10.1107/S160053681101261X
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