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A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole

The title complex, tetra­aqua­{1-[(1H-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole-κN (4)}(sulfato-κO)copper(II) sesquihydrate, [Cu(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·1.5H(2)O, is composed of one copper atom, one 1-[(2H-benzotriazol-1-yl)meth­yl]-1-H-1,2,4-triazole (bmt) ligand, one sulfate ligand, fou...

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Detalles Bibliográficos
Autores principales: Yang, Huai-xia, Zhang, Jun, Zhao, Dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089299/
https://www.ncbi.nlm.nih.gov/pubmed/21754321
http://dx.doi.org/10.1107/S1600536811013511
Descripción
Sumario:The title complex, tetra­aqua­{1-[(1H-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole-κN (4)}(sulfato-κO)copper(II) sesquihydrate, [Cu(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·1.5H(2)O, is composed of one copper atom, one 1-[(2H-benzotriazol-1-yl)meth­yl]-1-H-1,2,4-triazole (bmt) ligand, one sulfate ligand, four coordin­ated water mol­ecules and one and a half uncoordinated water mol­ecules. The Cu(II) atom is six-coordinated by one N atom from a bmt ligand and five O atoms from the monodentate sulfate ligand and four water mol­ecules in a distorted octa­hedral geometry. In the crystal, adjacent mol­ecules are linked through O—H⋯O and O—H⋯N hydrogen bonds involving the sulfate anion and the coordin­ated and uncoordinated water mol­ecules into a three-dimensional network.