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A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole
The title complex, tetraaqua{1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole-κN (4)}(sulfato-κO)copper(II) sesquihydrate, [Cu(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·1.5H(2)O, is composed of one copper atom, one 1-[(2H-benzotriazol-1-yl)methyl]-1-H-1,2,4-triazole (bmt) ligand, one sulfate ligand, fou...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089299/ https://www.ncbi.nlm.nih.gov/pubmed/21754321 http://dx.doi.org/10.1107/S1600536811013511 |
Sumario: | The title complex, tetraaqua{1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole-κN (4)}(sulfato-κO)copper(II) sesquihydrate, [Cu(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·1.5H(2)O, is composed of one copper atom, one 1-[(2H-benzotriazol-1-yl)methyl]-1-H-1,2,4-triazole (bmt) ligand, one sulfate ligand, four coordinated water molecules and one and a half uncoordinated water molecules. The Cu(II) atom is six-coordinated by one N atom from a bmt ligand and five O atoms from the monodentate sulfate ligand and four water molecules in a distorted octahedral geometry. In the crystal, adjacent molecules are linked through O—H⋯O and O—H⋯N hydrogen bonds involving the sulfate anion and the coordinated and uncoordinated water molecules into a three-dimensional network. |
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