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A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole
The title complex, tetraaqua{1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole-κN (4)}(sulfato-κO)copper(II) sesquihydrate, [Cu(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·1.5H(2)O, is composed of one copper atom, one 1-[(2H-benzotriazol-1-yl)methyl]-1-H-1,2,4-triazole (bmt) ligand, one sulfate ligand, fou...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089299/ https://www.ncbi.nlm.nih.gov/pubmed/21754321 http://dx.doi.org/10.1107/S1600536811013511 |
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author | Yang, Huai-xia Zhang, Jun Zhao, Dong |
author_facet | Yang, Huai-xia Zhang, Jun Zhao, Dong |
author_sort | Yang, Huai-xia |
collection | PubMed |
description | The title complex, tetraaqua{1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole-κN (4)}(sulfato-κO)copper(II) sesquihydrate, [Cu(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·1.5H(2)O, is composed of one copper atom, one 1-[(2H-benzotriazol-1-yl)methyl]-1-H-1,2,4-triazole (bmt) ligand, one sulfate ligand, four coordinated water molecules and one and a half uncoordinated water molecules. The Cu(II) atom is six-coordinated by one N atom from a bmt ligand and five O atoms from the monodentate sulfate ligand and four water molecules in a distorted octahedral geometry. In the crystal, adjacent molecules are linked through O—H⋯O and O—H⋯N hydrogen bonds involving the sulfate anion and the coordinated and uncoordinated water molecules into a three-dimensional network. |
format | Text |
id | pubmed-3089299 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30892992011-07-13 A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole Yang, Huai-xia Zhang, Jun Zhao, Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, tetraaqua{1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole-κN (4)}(sulfato-κO)copper(II) sesquihydrate, [Cu(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·1.5H(2)O, is composed of one copper atom, one 1-[(2H-benzotriazol-1-yl)methyl]-1-H-1,2,4-triazole (bmt) ligand, one sulfate ligand, four coordinated water molecules and one and a half uncoordinated water molecules. The Cu(II) atom is six-coordinated by one N atom from a bmt ligand and five O atoms from the monodentate sulfate ligand and four water molecules in a distorted octahedral geometry. In the crystal, adjacent molecules are linked through O—H⋯O and O—H⋯N hydrogen bonds involving the sulfate anion and the coordinated and uncoordinated water molecules into a three-dimensional network. International Union of Crystallography 2011-04-16 /pmc/articles/PMC3089299/ /pubmed/21754321 http://dx.doi.org/10.1107/S1600536811013511 Text en © Yang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Huai-xia Zhang, Jun Zhao, Dong A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole |
title | A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole |
title_full | A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole |
title_fullStr | A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole |
title_full_unstemmed | A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole |
title_short | A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole |
title_sort | new copper(ii) complex based on 1-[(1h-benzotriazol-1-yl)methyl]-1h-1,2,4-triazole |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089299/ https://www.ncbi.nlm.nih.gov/pubmed/21754321 http://dx.doi.org/10.1107/S1600536811013511 |
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