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A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole

The title complex, tetra­aqua­{1-[(1H-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole-κN (4)}(sulfato-κO)copper(II) sesquihydrate, [Cu(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·1.5H(2)O, is composed of one copper atom, one 1-[(2H-benzotriazol-1-yl)meth­yl]-1-H-1,2,4-triazole (bmt) ligand, one sulfate ligand, fou...

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Detalles Bibliográficos
Autores principales: Yang, Huai-xia, Zhang, Jun, Zhao, Dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089299/
https://www.ncbi.nlm.nih.gov/pubmed/21754321
http://dx.doi.org/10.1107/S1600536811013511
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author Yang, Huai-xia
Zhang, Jun
Zhao, Dong
author_facet Yang, Huai-xia
Zhang, Jun
Zhao, Dong
author_sort Yang, Huai-xia
collection PubMed
description The title complex, tetra­aqua­{1-[(1H-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole-κN (4)}(sulfato-κO)copper(II) sesquihydrate, [Cu(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·1.5H(2)O, is composed of one copper atom, one 1-[(2H-benzotriazol-1-yl)meth­yl]-1-H-1,2,4-triazole (bmt) ligand, one sulfate ligand, four coordin­ated water mol­ecules and one and a half uncoordinated water mol­ecules. The Cu(II) atom is six-coordinated by one N atom from a bmt ligand and five O atoms from the monodentate sulfate ligand and four water mol­ecules in a distorted octa­hedral geometry. In the crystal, adjacent mol­ecules are linked through O—H⋯O and O—H⋯N hydrogen bonds involving the sulfate anion and the coordin­ated and uncoordinated water mol­ecules into a three-dimensional network.
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spelling pubmed-30892992011-07-13 A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole Yang, Huai-xia Zhang, Jun Zhao, Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, tetra­aqua­{1-[(1H-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole-κN (4)}(sulfato-κO)copper(II) sesquihydrate, [Cu(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·1.5H(2)O, is composed of one copper atom, one 1-[(2H-benzotriazol-1-yl)meth­yl]-1-H-1,2,4-triazole (bmt) ligand, one sulfate ligand, four coordin­ated water mol­ecules and one and a half uncoordinated water mol­ecules. The Cu(II) atom is six-coordinated by one N atom from a bmt ligand and five O atoms from the monodentate sulfate ligand and four water mol­ecules in a distorted octa­hedral geometry. In the crystal, adjacent mol­ecules are linked through O—H⋯O and O—H⋯N hydrogen bonds involving the sulfate anion and the coordin­ated and uncoordinated water mol­ecules into a three-dimensional network. International Union of Crystallography 2011-04-16 /pmc/articles/PMC3089299/ /pubmed/21754321 http://dx.doi.org/10.1107/S1600536811013511 Text en © Yang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Huai-xia
Zhang, Jun
Zhao, Dong
A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole
title A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole
title_full A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole
title_fullStr A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole
title_full_unstemmed A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole
title_short A new copper(II) complex based on 1-[(1H-benzotriazol-1-yl)meth­yl]-1H-1,2,4-triazole
title_sort new copper(ii) complex based on 1-[(1h-benzotriazol-1-yl)meth­yl]-1h-1,2,4-triazole
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089299/
https://www.ncbi.nlm.nih.gov/pubmed/21754321
http://dx.doi.org/10.1107/S1600536811013511
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