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4-({[(E)-Pyridin-3-ylmethylidene]amino}methyl)cyclohexanecarboxylic acid
The title compound, C(14)H(18)N(2)O(2), contains two geometrically different molecules in the asymmetric unit: the basal plane of the cyclohexane chair and the N-[pyridin-3-ylmethylidene]methanamine moiety are oriented at dihedral angles of 71.77 (7)° and 83.42 (8)°. In the crystal, the molecul...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089300/ https://www.ncbi.nlm.nih.gov/pubmed/21754384 http://dx.doi.org/10.1107/S1600536811011779 |
Sumario: | The title compound, C(14)H(18)N(2)O(2), contains two geometrically different molecules in the asymmetric unit: the basal plane of the cyclohexane chair and the N-[pyridin-3-ylmethylidene]methanamine moiety are oriented at dihedral angles of 71.77 (7)° and 83.42 (8)°. In the crystal, the molecules are linked by O—H⋯N hydrogen bonds, generating C(13) head-to-tail chains extending along the base vector [103]. R (2) (2)(26) ring motifs are formed due to the C—H⋯·O interactions that link neighbouring chains. There also exist π–π interactions [centroid–centroid separation = 3.6925 (12) Å] between the symmetry-related pyridine rings of one of the independent molecules. |
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