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4-({[(E)-Pyridin-3-ylmethylidene]amino}methyl)cyclohexanecarboxylic acid
The title compound, C(14)H(18)N(2)O(2), contains two geometrically different molecules in the asymmetric unit: the basal plane of the cyclohexane chair and the N-[pyridin-3-ylmethylidene]methanamine moiety are oriented at dihedral angles of 71.77 (7)° and 83.42 (8)°. In the crystal, the molecul...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089300/ https://www.ncbi.nlm.nih.gov/pubmed/21754384 http://dx.doi.org/10.1107/S1600536811011779 |
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author | Nisar, Muhammad Ali, Ihsan Tahir, M. Nawaz Qayum, Mughal Marwat, Inamullah Khan |
author_facet | Nisar, Muhammad Ali, Ihsan Tahir, M. Nawaz Qayum, Mughal Marwat, Inamullah Khan |
author_sort | Nisar, Muhammad |
collection | PubMed |
description | The title compound, C(14)H(18)N(2)O(2), contains two geometrically different molecules in the asymmetric unit: the basal plane of the cyclohexane chair and the N-[pyridin-3-ylmethylidene]methanamine moiety are oriented at dihedral angles of 71.77 (7)° and 83.42 (8)°. In the crystal, the molecules are linked by O—H⋯N hydrogen bonds, generating C(13) head-to-tail chains extending along the base vector [103]. R (2) (2)(26) ring motifs are formed due to the C—H⋯·O interactions that link neighbouring chains. There also exist π–π interactions [centroid–centroid separation = 3.6925 (12) Å] between the symmetry-related pyridine rings of one of the independent molecules. |
format | Text |
id | pubmed-3089300 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30893002011-07-13 4-({[(E)-Pyridin-3-ylmethylidene]amino}methyl)cyclohexanecarboxylic acid Nisar, Muhammad Ali, Ihsan Tahir, M. Nawaz Qayum, Mughal Marwat, Inamullah Khan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(18)N(2)O(2), contains two geometrically different molecules in the asymmetric unit: the basal plane of the cyclohexane chair and the N-[pyridin-3-ylmethylidene]methanamine moiety are oriented at dihedral angles of 71.77 (7)° and 83.42 (8)°. In the crystal, the molecules are linked by O—H⋯N hydrogen bonds, generating C(13) head-to-tail chains extending along the base vector [103]. R (2) (2)(26) ring motifs are formed due to the C—H⋯·O interactions that link neighbouring chains. There also exist π–π interactions [centroid–centroid separation = 3.6925 (12) Å] between the symmetry-related pyridine rings of one of the independent molecules. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089300/ /pubmed/21754384 http://dx.doi.org/10.1107/S1600536811011779 Text en © Nisar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Nisar, Muhammad Ali, Ihsan Tahir, M. Nawaz Qayum, Mughal Marwat, Inamullah Khan 4-({[(E)-Pyridin-3-ylmethylidene]amino}methyl)cyclohexanecarboxylic acid |
title | 4-({[(E)-Pyridin-3-ylmethylidene]amino}methyl)cyclohexanecarboxylic acid |
title_full | 4-({[(E)-Pyridin-3-ylmethylidene]amino}methyl)cyclohexanecarboxylic acid |
title_fullStr | 4-({[(E)-Pyridin-3-ylmethylidene]amino}methyl)cyclohexanecarboxylic acid |
title_full_unstemmed | 4-({[(E)-Pyridin-3-ylmethylidene]amino}methyl)cyclohexanecarboxylic acid |
title_short | 4-({[(E)-Pyridin-3-ylmethylidene]amino}methyl)cyclohexanecarboxylic acid |
title_sort | 4-({[(e)-pyridin-3-ylmethylidene]amino}methyl)cyclohexanecarboxylic acid |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089300/ https://www.ncbi.nlm.nih.gov/pubmed/21754384 http://dx.doi.org/10.1107/S1600536811011779 |
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