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4-({[(E)-Pyridin-3-yl­methyl­idene]amino}­meth­yl)cyclo­hexa­necarb­oxy­lic acid

The title compound, C(14)H(18)N(2)O(2), contains two geometrically different mol­ecules in the asymmetric unit: the basal plane of the cyclo­hexane chair and the N-[pyridin-3-yl­methyl­idene]methanamine moiety are oriented at dihedral angles of 71.77 (7)° and 83.42 (8)°. In the crystal, the mol­ecul...

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Autores principales: Nisar, Muhammad, Ali, Ihsan, Tahir, M. Nawaz, Qayum, Mughal, Marwat, Inamullah Khan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089300/
https://www.ncbi.nlm.nih.gov/pubmed/21754384
http://dx.doi.org/10.1107/S1600536811011779
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author Nisar, Muhammad
Ali, Ihsan
Tahir, M. Nawaz
Qayum, Mughal
Marwat, Inamullah Khan
author_facet Nisar, Muhammad
Ali, Ihsan
Tahir, M. Nawaz
Qayum, Mughal
Marwat, Inamullah Khan
author_sort Nisar, Muhammad
collection PubMed
description The title compound, C(14)H(18)N(2)O(2), contains two geometrically different mol­ecules in the asymmetric unit: the basal plane of the cyclo­hexane chair and the N-[pyridin-3-yl­methyl­idene]methanamine moiety are oriented at dihedral angles of 71.77 (7)° and 83.42 (8)°. In the crystal, the mol­ecules are linked by O—H⋯N hydrogen bonds, generating C(13) head-to-tail chains extending along the base vector [103]. R (2) (2)(26) ring motifs are formed due to the C—H⋯·O inter­actions that link neighbouring chains. There also exist π–π inter­actions [centroid–centroid separation = 3.6925 (12) Å] between the symmetry-related pyridine rings of one of the independent mol­ecules.
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spelling pubmed-30893002011-07-13 4-({[(E)-Pyridin-3-yl­methyl­idene]amino}­meth­yl)cyclo­hexa­necarb­oxy­lic acid Nisar, Muhammad Ali, Ihsan Tahir, M. Nawaz Qayum, Mughal Marwat, Inamullah Khan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(18)N(2)O(2), contains two geometrically different mol­ecules in the asymmetric unit: the basal plane of the cyclo­hexane chair and the N-[pyridin-3-yl­methyl­idene]methanamine moiety are oriented at dihedral angles of 71.77 (7)° and 83.42 (8)°. In the crystal, the mol­ecules are linked by O—H⋯N hydrogen bonds, generating C(13) head-to-tail chains extending along the base vector [103]. R (2) (2)(26) ring motifs are formed due to the C—H⋯·O inter­actions that link neighbouring chains. There also exist π–π inter­actions [centroid–centroid separation = 3.6925 (12) Å] between the symmetry-related pyridine rings of one of the independent mol­ecules. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089300/ /pubmed/21754384 http://dx.doi.org/10.1107/S1600536811011779 Text en © Nisar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nisar, Muhammad
Ali, Ihsan
Tahir, M. Nawaz
Qayum, Mughal
Marwat, Inamullah Khan
4-({[(E)-Pyridin-3-yl­methyl­idene]amino}­meth­yl)cyclo­hexa­necarb­oxy­lic acid
title 4-({[(E)-Pyridin-3-yl­methyl­idene]amino}­meth­yl)cyclo­hexa­necarb­oxy­lic acid
title_full 4-({[(E)-Pyridin-3-yl­methyl­idene]amino}­meth­yl)cyclo­hexa­necarb­oxy­lic acid
title_fullStr 4-({[(E)-Pyridin-3-yl­methyl­idene]amino}­meth­yl)cyclo­hexa­necarb­oxy­lic acid
title_full_unstemmed 4-({[(E)-Pyridin-3-yl­methyl­idene]amino}­meth­yl)cyclo­hexa­necarb­oxy­lic acid
title_short 4-({[(E)-Pyridin-3-yl­methyl­idene]amino}­meth­yl)cyclo­hexa­necarb­oxy­lic acid
title_sort 4-({[(e)-pyridin-3-yl­methyl­idene]amino}­meth­yl)cyclo­hexa­necarb­oxy­lic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089300/
https://www.ncbi.nlm.nih.gov/pubmed/21754384
http://dx.doi.org/10.1107/S1600536811011779
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