Tetra­kis­(μ-3-meth­oxy­benzoato-κ(2) O (1):O (1′))bis[acetonitrilecopper(II)]

The centrosymmetric binuclear Cu(II) title complex, [Cu(2)(C(8)H(7)O(3))(4)(CH(3)CN)(2)], has a paddle-wheel-type structure [Cu—Cu distance = 2.6433 (3) Å]. Each Cu(II) ion is coordin­ated by four O atoms from two 3-meth­oxy­benzoate ligands and one acetonitrile N atom in a square-pyramidal geometry...

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Detalles Bibliográficos
Autores principales: Kar, Sanjib, Garai, Antara, Bala, Sukhen, Purohit, Chandra Shekhar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089301/
https://www.ncbi.nlm.nih.gov/pubmed/21754290
http://dx.doi.org/10.1107/S1600536811012074
Descripción
Sumario:The centrosymmetric binuclear Cu(II) title complex, [Cu(2)(C(8)H(7)O(3))(4)(CH(3)CN)(2)], has a paddle-wheel-type structure [Cu—Cu distance = 2.6433 (3) Å]. Each Cu(II) ion is coordin­ated by four O atoms from two 3-meth­oxy­benzoate ligands and one acetonitrile N atom in a square-pyramidal geometry.

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