N-Methyl-4-(4-pivalamido­phenyl­sulfan­yl)picolinamide hemihydrate

In the title compound, C(18)H(21)N(3)O(2)S·0.5H(2)O, the benzene ring makes dihedral angles of 88.59 (6) and 40.74 (8)° with the pyridine ring and the amide group, respectively. The water O atom lies on a twofold axis. In the crystal, the organic mol­ecules and the water mol­ecules are linked via O—...

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Detalles Bibliográficos
Autores principales: Ye, Ting-Hong, Huang, Ting-Ting, Shi, Yao-Jie, Xiong, Ying, Yu, Luo-Ting
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089303/
https://www.ncbi.nlm.nih.gov/pubmed/21754418
http://dx.doi.org/10.1107/S1600536811012268
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author Ye, Ting-Hong
Huang, Ting-Ting
Shi, Yao-Jie
Xiong, Ying
Yu, Luo-Ting
author_facet Ye, Ting-Hong
Huang, Ting-Ting
Shi, Yao-Jie
Xiong, Ying
Yu, Luo-Ting
author_sort Ye, Ting-Hong
collection PubMed
description In the title compound, C(18)H(21)N(3)O(2)S·0.5H(2)O, the benzene ring makes dihedral angles of 88.59 (6) and 40.74 (8)° with the pyridine ring and the amide group, respectively. The water O atom lies on a twofold axis. In the crystal, the organic mol­ecules and the water mol­ecules are linked via O—H⋯O hydrogen bonds, while the organic mol­ecules are connected to each other via N—H⋯O hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-30893032011-07-13 N-Methyl-4-(4-pivalamido­phenyl­sulfan­yl)picolinamide hemihydrate Ye, Ting-Hong Huang, Ting-Ting Shi, Yao-Jie Xiong, Ying Yu, Luo-Ting Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(21)N(3)O(2)S·0.5H(2)O, the benzene ring makes dihedral angles of 88.59 (6) and 40.74 (8)° with the pyridine ring and the amide group, respectively. The water O atom lies on a twofold axis. In the crystal, the organic mol­ecules and the water mol­ecules are linked via O—H⋯O hydrogen bonds, while the organic mol­ecules are connected to each other via N—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089303/ /pubmed/21754418 http://dx.doi.org/10.1107/S1600536811012268 Text en © Ye et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ye, Ting-Hong
Huang, Ting-Ting
Shi, Yao-Jie
Xiong, Ying
Yu, Luo-Ting
N-Methyl-4-(4-pivalamido­phenyl­sulfan­yl)picolinamide hemihydrate
title N-Methyl-4-(4-pivalamido­phenyl­sulfan­yl)picolinamide hemihydrate
title_full N-Methyl-4-(4-pivalamido­phenyl­sulfan­yl)picolinamide hemihydrate
title_fullStr N-Methyl-4-(4-pivalamido­phenyl­sulfan­yl)picolinamide hemihydrate
title_full_unstemmed N-Methyl-4-(4-pivalamido­phenyl­sulfan­yl)picolinamide hemihydrate
title_short N-Methyl-4-(4-pivalamido­phenyl­sulfan­yl)picolinamide hemihydrate
title_sort n-methyl-4-(4-pivalamido­phenyl­sulfan­yl)picolinamide hemihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089303/
https://www.ncbi.nlm.nih.gov/pubmed/21754418
http://dx.doi.org/10.1107/S1600536811012268
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AT yuluoting nmethyl44pivalamidophenylsulfanylpicolinamidehemihydrate

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