[N-(3-Meth­oxy-2-oxidobenzyl­idene-κO (2))threoninato-κ(2) O (1),N](1,10-phenanthroline-κ(2) N,N′)copper(II) hemihydrate

In the title complex, [Cu(C(12)H(13)NO(5))(C(12)H(8)N(2))]·0.5H(2)O, the Cu(II) ion is five-coordinated by one N atom and two O atoms from a tridentate Schiff base ligand, derived from the condensation of l-threonine and o-vanillin, and two N atoms from a 1,10-phenanthroline ligand in a distorted sq...

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Detalles Bibliográficos
Autores principales: Jing, Buqin, Li, Lianzhi, Dong, Jianfang, Li, Jinghong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089306/
https://www.ncbi.nlm.nih.gov/pubmed/21754276
http://dx.doi.org/10.1107/S1600536811012049
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author Jing, Buqin
Li, Lianzhi
Dong, Jianfang
Li, Jinghong
author_facet Jing, Buqin
Li, Lianzhi
Dong, Jianfang
Li, Jinghong
author_sort Jing, Buqin
collection PubMed
description In the title complex, [Cu(C(12)H(13)NO(5))(C(12)H(8)N(2))]·0.5H(2)O, the Cu(II) ion is five-coordinated by one N atom and two O atoms from a tridentate Schiff base ligand, derived from the condensation of l-threonine and o-vanillin, and two N atoms from a 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. In the crystal, inter­molecular O—H⋯O hydrogen bonds form a one-dimensional left-handed helical structureextending parallel to [001]. The water molecule of crystallization shows half-occupancy.
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spelling pubmed-30893062011-07-13 [N-(3-Meth­oxy-2-oxidobenzyl­idene-κO (2))threoninato-κ(2) O (1),N](1,10-phenanthroline-κ(2) N,N′)copper(II) hemihydrate Jing, Buqin Li, Lianzhi Dong, Jianfang Li, Jinghong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(12)H(13)NO(5))(C(12)H(8)N(2))]·0.5H(2)O, the Cu(II) ion is five-coordinated by one N atom and two O atoms from a tridentate Schiff base ligand, derived from the condensation of l-threonine and o-vanillin, and two N atoms from a 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. In the crystal, inter­molecular O—H⋯O hydrogen bonds form a one-dimensional left-handed helical structureextending parallel to [001]. The water molecule of crystallization shows half-occupancy. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089306/ /pubmed/21754276 http://dx.doi.org/10.1107/S1600536811012049 Text en © Jing et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jing, Buqin
Li, Lianzhi
Dong, Jianfang
Li, Jinghong
[N-(3-Meth­oxy-2-oxidobenzyl­idene-κO (2))threoninato-κ(2) O (1),N](1,10-phenanthroline-κ(2) N,N′)copper(II) hemihydrate
title [N-(3-Meth­oxy-2-oxidobenzyl­idene-κO (2))threoninato-κ(2) O (1),N](1,10-phenanthroline-κ(2) N,N′)copper(II) hemihydrate
title_full [N-(3-Meth­oxy-2-oxidobenzyl­idene-κO (2))threoninato-κ(2) O (1),N](1,10-phenanthroline-κ(2) N,N′)copper(II) hemihydrate
title_fullStr [N-(3-Meth­oxy-2-oxidobenzyl­idene-κO (2))threoninato-κ(2) O (1),N](1,10-phenanthroline-κ(2) N,N′)copper(II) hemihydrate
title_full_unstemmed [N-(3-Meth­oxy-2-oxidobenzyl­idene-κO (2))threoninato-κ(2) O (1),N](1,10-phenanthroline-κ(2) N,N′)copper(II) hemihydrate
title_short [N-(3-Meth­oxy-2-oxidobenzyl­idene-κO (2))threoninato-κ(2) O (1),N](1,10-phenanthroline-κ(2) N,N′)copper(II) hemihydrate
title_sort [n-(3-meth­oxy-2-oxidobenzyl­idene-κo (2))threoninato-κ(2) o (1),n](1,10-phenanthroline-κ(2) n,n′)copper(ii) hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089306/
https://www.ncbi.nlm.nih.gov/pubmed/21754276
http://dx.doi.org/10.1107/S1600536811012049
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AT dongjianfang n3methoxy2oxidobenzylideneko2threoninatok2o1n110phenanthrolinek2nncopperiihemihydrate
AT lijinghong n3methoxy2oxidobenzylideneko2threoninatok2o1n110phenanthrolinek2nncopperiihemihydrate

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