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Diaquabis(N,N-diethylnicotinamide-κN (1))bis(4-ethylbenzoato-κO)cobalt(II)
The title Co(II) complex, [Co(C(9)H(9)O(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains two 4-ethylbenzoate (PEB), two monodentate diethylnicotinamide (DENA) ligands and two water molecules. The four O atoms in the equatorial plane around the Co(II) ion form a slightly distorted square-planar arr...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089307/ https://www.ncbi.nlm.nih.gov/pubmed/21754332 http://dx.doi.org/10.1107/S1600536811014188 |
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author | Necefoğlu, Hacali Maracı, Ali Özbek, Füreya Elif Tercan, Barış Hökelek, Tuncer |
author_facet | Necefoğlu, Hacali Maracı, Ali Özbek, Füreya Elif Tercan, Barış Hökelek, Tuncer |
author_sort | Necefoğlu, Hacali |
collection | PubMed |
description | The title Co(II) complex, [Co(C(9)H(9)O(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains two 4-ethylbenzoate (PEB), two monodentate diethylnicotinamide (DENA) ligands and two water molecules. The four O atoms in the equatorial plane around the Co(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. Intramolecular O—H⋯O hydrogen bonds link the water molecules to the carboxylate groups. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 4.52 (18) and 4.56 (18)°, while the pyridine rings and the benzene rings are oriented at dihedral angles of 7.76 (10) and 5.67 (13)°. In the crystal, intermolecular O—H⋯O hydrogen bonds link the molecules into chains propagating along [010]. C—H⋯O interactions and a π–π contact between the pyridine rings [centroid–centroid distance = 3.476 (2) Å] are also observed. |
format | Text |
id | pubmed-3089307 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30893072011-07-13 Diaquabis(N,N-diethylnicotinamide-κN (1))bis(4-ethylbenzoato-κO)cobalt(II) Necefoğlu, Hacali Maracı, Ali Özbek, Füreya Elif Tercan, Barış Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Co(II) complex, [Co(C(9)H(9)O(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains two 4-ethylbenzoate (PEB), two monodentate diethylnicotinamide (DENA) ligands and two water molecules. The four O atoms in the equatorial plane around the Co(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. Intramolecular O—H⋯O hydrogen bonds link the water molecules to the carboxylate groups. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 4.52 (18) and 4.56 (18)°, while the pyridine rings and the benzene rings are oriented at dihedral angles of 7.76 (10) and 5.67 (13)°. In the crystal, intermolecular O—H⋯O hydrogen bonds link the molecules into chains propagating along [010]. C—H⋯O interactions and a π–π contact between the pyridine rings [centroid–centroid distance = 3.476 (2) Å] are also observed. International Union of Crystallography 2011-04-22 /pmc/articles/PMC3089307/ /pubmed/21754332 http://dx.doi.org/10.1107/S1600536811014188 Text en © Necefoğlu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Necefoğlu, Hacali Maracı, Ali Özbek, Füreya Elif Tercan, Barış Hökelek, Tuncer Diaquabis(N,N-diethylnicotinamide-κN (1))bis(4-ethylbenzoato-κO)cobalt(II) |
title | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis(4-ethylbenzoato-κO)cobalt(II) |
title_full | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis(4-ethylbenzoato-κO)cobalt(II) |
title_fullStr | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis(4-ethylbenzoato-κO)cobalt(II) |
title_full_unstemmed | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis(4-ethylbenzoato-κO)cobalt(II) |
title_short | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis(4-ethylbenzoato-κO)cobalt(II) |
title_sort | diaquabis(n,n-diethylnicotinamide-κn
(1))bis(4-ethylbenzoato-κo)cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089307/ https://www.ncbi.nlm.nih.gov/pubmed/21754332 http://dx.doi.org/10.1107/S1600536811014188 |
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