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Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis­(4-ethyl­benzoato-κO)cobalt(II)

The title Co(II) complex, [Co(C(9)H(9)O(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains two 4-ethyl­benzoate (PEB), two monodentate diethyl­nicotinamide (DENA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the Co(II) ion form a slightly distorted square-planar arr...

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Autores principales: Necefoğlu, Hacali, Maracı, Ali, Özbek, Füreya Elif, Tercan, Barış, Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089307/
https://www.ncbi.nlm.nih.gov/pubmed/21754332
http://dx.doi.org/10.1107/S1600536811014188
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author Necefoğlu, Hacali
Maracı, Ali
Özbek, Füreya Elif
Tercan, Barış
Hökelek, Tuncer
author_facet Necefoğlu, Hacali
Maracı, Ali
Özbek, Füreya Elif
Tercan, Barış
Hökelek, Tuncer
author_sort Necefoğlu, Hacali
collection PubMed
description The title Co(II) complex, [Co(C(9)H(9)O(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains two 4-ethyl­benzoate (PEB), two monodentate diethyl­nicotinamide (DENA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the Co(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. Intra­molecular O—H⋯O hydrogen bonds link the water mol­ecules to the carboxyl­ate groups. The dihedral angles between the carboxyl­ate groups and the adjacent benzene rings are 4.52 (18) and 4.56 (18)°, while the pyridine rings and the benzene rings are oriented at dihedral angles of 7.76 (10) and 5.67 (13)°. In the crystal, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into chains propagating along [010]. C—H⋯O inter­actions and a π–π contact between the pyridine rings [centroid–centroid distance = 3.476 (2) Å] are also observed.
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spelling pubmed-30893072011-07-13 Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis­(4-ethyl­benzoato-κO)cobalt(II) Necefoğlu, Hacali Maracı, Ali Özbek, Füreya Elif Tercan, Barış Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Co(II) complex, [Co(C(9)H(9)O(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains two 4-ethyl­benzoate (PEB), two monodentate diethyl­nicotinamide (DENA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the Co(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. Intra­molecular O—H⋯O hydrogen bonds link the water mol­ecules to the carboxyl­ate groups. The dihedral angles between the carboxyl­ate groups and the adjacent benzene rings are 4.52 (18) and 4.56 (18)°, while the pyridine rings and the benzene rings are oriented at dihedral angles of 7.76 (10) and 5.67 (13)°. In the crystal, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules into chains propagating along [010]. C—H⋯O inter­actions and a π–π contact between the pyridine rings [centroid–centroid distance = 3.476 (2) Å] are also observed. International Union of Crystallography 2011-04-22 /pmc/articles/PMC3089307/ /pubmed/21754332 http://dx.doi.org/10.1107/S1600536811014188 Text en © Necefoğlu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Necefoğlu, Hacali
Maracı, Ali
Özbek, Füreya Elif
Tercan, Barış
Hökelek, Tuncer
Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis­(4-ethyl­benzoato-κO)cobalt(II)
title Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis­(4-ethyl­benzoato-κO)cobalt(II)
title_full Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis­(4-ethyl­benzoato-κO)cobalt(II)
title_fullStr Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis­(4-ethyl­benzoato-κO)cobalt(II)
title_full_unstemmed Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis­(4-ethyl­benzoato-κO)cobalt(II)
title_short Diaqua­bis­(N,N-diethyl­nicotinamide-κN (1))bis­(4-ethyl­benzoato-κO)cobalt(II)
title_sort diaqua­bis­(n,n-diethyl­nicotinamide-κn (1))bis­(4-ethyl­benzoato-κo)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089307/
https://www.ncbi.nlm.nih.gov/pubmed/21754332
http://dx.doi.org/10.1107/S1600536811014188
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