cyclo-Tetrakis(μ(2)-3-sulfidopropyl-κ(3) C (1),S:S)tetrakis[chloridocobalt(III)]

In the centrosymmetric title compound, [Co(4)Cl(4)(C(3)H(6)S)](4)], the two independent Co(III) ions are each coordinated in a distorted tetra­hedral geometry by one C, one Cl and two S atoms. The mol­ecules are stabilized by C—H⋯Cl hydrogen bonds. In the crystal, inter­molecular C—H⋯Cl and C—H⋯S hy...

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Detalles Bibliográficos
Autores principales: Awan, Shafique Ahmad, Tahir, M. Nawaz, Muhammad, Iram Khushi, Ahmad, Saeed, Tariq, Muhammad Ilyas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089308/
https://www.ncbi.nlm.nih.gov/pubmed/21754303
http://dx.doi.org/10.1107/S1600536811013067
Descripción
Sumario:In the centrosymmetric title compound, [Co(4)Cl(4)(C(3)H(6)S)](4)], the two independent Co(III) ions are each coordinated in a distorted tetra­hedral geometry by one C, one Cl and two S atoms. The mol­ecules are stabilized by C—H⋯Cl hydrogen bonds. In the crystal, inter­molecular C—H⋯Cl and C—H⋯S hydrogen bonds with R (2) (2)(8), R (4) (2)(8) and R (2) (2)(6) ring motifs generate a polymeric network.

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