cyclo-Tetrakis(μ(2)-3-sulfidopropyl-κ(3) C (1),S:S)tetrakis[chloridocobalt(III)]

In the centrosymmetric title compound, [Co(4)Cl(4)(C(3)H(6)S)](4)], the two independent Co(III) ions are each coordinated in a distorted tetra­hedral geometry by one C, one Cl and two S atoms. The mol­ecules are stabilized by C—H⋯Cl hydrogen bonds. In the crystal, inter­molecular C—H⋯Cl and C—H⋯S hy...

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Autores principales: Awan, Shafique Ahmad, Tahir, M. Nawaz, Muhammad, Iram Khushi, Ahmad, Saeed, Tariq, Muhammad Ilyas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089308/
https://www.ncbi.nlm.nih.gov/pubmed/21754303
http://dx.doi.org/10.1107/S1600536811013067
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author Awan, Shafique Ahmad
Tahir, M. Nawaz
Muhammad, Iram Khushi
Ahmad, Saeed
Tariq, Muhammad Ilyas
author_facet Awan, Shafique Ahmad
Tahir, M. Nawaz
Muhammad, Iram Khushi
Ahmad, Saeed
Tariq, Muhammad Ilyas
author_sort Awan, Shafique Ahmad
collection PubMed
description In the centrosymmetric title compound, [Co(4)Cl(4)(C(3)H(6)S)](4)], the two independent Co(III) ions are each coordinated in a distorted tetra­hedral geometry by one C, one Cl and two S atoms. The mol­ecules are stabilized by C—H⋯Cl hydrogen bonds. In the crystal, inter­molecular C—H⋯Cl and C—H⋯S hydrogen bonds with R (2) (2)(8), R (4) (2)(8) and R (2) (2)(6) ring motifs generate a polymeric network.
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spelling pubmed-30893082011-07-13 cyclo-Tetrakis(μ(2)-3-sulfidopropyl-κ(3) C (1),S:S)tetrakis[chloridocobalt(III)] Awan, Shafique Ahmad Tahir, M. Nawaz Muhammad, Iram Khushi Ahmad, Saeed Tariq, Muhammad Ilyas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title compound, [Co(4)Cl(4)(C(3)H(6)S)](4)], the two independent Co(III) ions are each coordinated in a distorted tetra­hedral geometry by one C, one Cl and two S atoms. The mol­ecules are stabilized by C—H⋯Cl hydrogen bonds. In the crystal, inter­molecular C—H⋯Cl and C—H⋯S hydrogen bonds with R (2) (2)(8), R (4) (2)(8) and R (2) (2)(6) ring motifs generate a polymeric network. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089308/ /pubmed/21754303 http://dx.doi.org/10.1107/S1600536811013067 Text en © Awan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Awan, Shafique Ahmad
Tahir, M. Nawaz
Muhammad, Iram Khushi
Ahmad, Saeed
Tariq, Muhammad Ilyas
cyclo-Tetrakis(μ(2)-3-sulfidopropyl-κ(3) C (1),S:S)tetrakis[chloridocobalt(III)]
title cyclo-Tetrakis(μ(2)-3-sulfidopropyl-κ(3) C (1),S:S)tetrakis[chloridocobalt(III)]
title_full cyclo-Tetrakis(μ(2)-3-sulfidopropyl-κ(3) C (1),S:S)tetrakis[chloridocobalt(III)]
title_fullStr cyclo-Tetrakis(μ(2)-3-sulfidopropyl-κ(3) C (1),S:S)tetrakis[chloridocobalt(III)]
title_full_unstemmed cyclo-Tetrakis(μ(2)-3-sulfidopropyl-κ(3) C (1),S:S)tetrakis[chloridocobalt(III)]
title_short cyclo-Tetrakis(μ(2)-3-sulfidopropyl-κ(3) C (1),S:S)tetrakis[chloridocobalt(III)]
title_sort cyclo-tetrakis(μ(2)-3-sulfidopropyl-κ(3) c (1),s:s)tetrakis[chloridocobalt(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089308/
https://www.ncbi.nlm.nih.gov/pubmed/21754303
http://dx.doi.org/10.1107/S1600536811013067
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