catena-Poly[[dichloridocopper(II)]-μ-4,4′-bis­(benzimidazol-1-yl)biphen­yl]

In the title compound, [CuCl(2)(C(26)H(18)N(4))](n), the Cu(II) ion is four-coordinated by two N atoms from two 4,4′-bis­(benzo­imidazol-1-yl)biphenyl ligands and two chloride anions, in a slightly distorted tetra­hedral environment. The biphenyl ligand acts as a linear bidentate ligand, connecting...

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Detalles Bibliográficos
Autores principales: Xiao, Dan-Ni, Pan, Hong-Yan, Yao, Min, Xie, Gang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089309/
https://www.ncbi.nlm.nih.gov/pubmed/21754264
http://dx.doi.org/10.1107/S1600536811011421
Descripción
Sumario:In the title compound, [CuCl(2)(C(26)H(18)N(4))](n), the Cu(II) ion is four-coordinated by two N atoms from two 4,4′-bis­(benzo­imidazol-1-yl)biphenyl ligands and two chloride anions, in a slightly distorted tetra­hedral environment. The biphenyl ligand acts as a linear bidentate ligand, connecting the metal atoms into an infinite chain parallel to [101]. In the biphenyl ligand, the two benzene rings make a dihedral angle of 33.19 (7)°.

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