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2-[2-(1H-Imidazol-3-ium-5-yl)eth­yl]-3-(pyridin-2-yl)-2H-imidazo[1,5-a]pyridin-4-ium bis­(perchlorate)

In the title mol­ecular salt, C(17)H(17)N(5) (+)·2ClO(4) (−), the dihedral angles between the fused-ring system and the pendant five- and six-membered heterocyclic rings are 6.4 (2) and 41.29 (19)°, respectively. The O atoms of both perchlorate anions are disordered over two sets of sites with occup...

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Detalles Bibliográficos
Autores principales: Türkyılmaz, Murat, Baran, Yakup, Özdemir, Namık
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089310/
https://www.ncbi.nlm.nih.gov/pubmed/21754563
http://dx.doi.org/10.1107/S1600536811015625
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author Türkyılmaz, Murat
Baran, Yakup
Özdemir, Namık
author_facet Türkyılmaz, Murat
Baran, Yakup
Özdemir, Namık
author_sort Türkyılmaz, Murat
collection PubMed
description In the title mol­ecular salt, C(17)H(17)N(5) (+)·2ClO(4) (−), the dihedral angles between the fused-ring system and the pendant five- and six-membered heterocyclic rings are 6.4 (2) and 41.29 (19)°, respectively. The O atoms of both perchlorate anions are disordered over two sets of sites with occupancy ratios of 0.614 (8):0.386 (8) and 0.591 (7):0.409 (7). An intra­molecular C—H⋯N contact occurs in the cation. In the crystal, the components are linked by N—H⋯O and C—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid separation = 3.642 (3) Å].
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spelling pubmed-30893102011-07-13 2-[2-(1H-Imidazol-3-ium-5-yl)eth­yl]-3-(pyridin-2-yl)-2H-imidazo[1,5-a]pyridin-4-ium bis­(perchlorate) Türkyılmaz, Murat Baran, Yakup Özdemir, Namık Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecular salt, C(17)H(17)N(5) (+)·2ClO(4) (−), the dihedral angles between the fused-ring system and the pendant five- and six-membered heterocyclic rings are 6.4 (2) and 41.29 (19)°, respectively. The O atoms of both perchlorate anions are disordered over two sets of sites with occupancy ratios of 0.614 (8):0.386 (8) and 0.591 (7):0.409 (7). An intra­molecular C—H⋯N contact occurs in the cation. In the crystal, the components are linked by N—H⋯O and C—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid separation = 3.642 (3) Å]. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089310/ /pubmed/21754563 http://dx.doi.org/10.1107/S1600536811015625 Text en © Türkyılmaz et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Türkyılmaz, Murat
Baran, Yakup
Özdemir, Namık
2-[2-(1H-Imidazol-3-ium-5-yl)eth­yl]-3-(pyridin-2-yl)-2H-imidazo[1,5-a]pyridin-4-ium bis­(perchlorate)
title 2-[2-(1H-Imidazol-3-ium-5-yl)eth­yl]-3-(pyridin-2-yl)-2H-imidazo[1,5-a]pyridin-4-ium bis­(perchlorate)
title_full 2-[2-(1H-Imidazol-3-ium-5-yl)eth­yl]-3-(pyridin-2-yl)-2H-imidazo[1,5-a]pyridin-4-ium bis­(perchlorate)
title_fullStr 2-[2-(1H-Imidazol-3-ium-5-yl)eth­yl]-3-(pyridin-2-yl)-2H-imidazo[1,5-a]pyridin-4-ium bis­(perchlorate)
title_full_unstemmed 2-[2-(1H-Imidazol-3-ium-5-yl)eth­yl]-3-(pyridin-2-yl)-2H-imidazo[1,5-a]pyridin-4-ium bis­(perchlorate)
title_short 2-[2-(1H-Imidazol-3-ium-5-yl)eth­yl]-3-(pyridin-2-yl)-2H-imidazo[1,5-a]pyridin-4-ium bis­(perchlorate)
title_sort 2-[2-(1h-imidazol-3-ium-5-yl)eth­yl]-3-(pyridin-2-yl)-2h-imidazo[1,5-a]pyridin-4-ium bis­(perchlorate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089310/
https://www.ncbi.nlm.nih.gov/pubmed/21754563
http://dx.doi.org/10.1107/S1600536811015625
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AT ozdemirnamık 221himidazol3ium5ylethyl3pyridin2yl2himidazo15apyridin4iumbisperchlorate