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2-[2-(1H-Imidazol-3-ium-5-yl)ethyl]-3-(pyridin-2-yl)-2H-imidazo[1,5-a]pyridin-4-ium bis(perchlorate)
In the title molecular salt, C(17)H(17)N(5) (+)·2ClO(4) (−), the dihedral angles between the fused-ring system and the pendant five- and six-membered heterocyclic rings are 6.4 (2) and 41.29 (19)°, respectively. The O atoms of both perchlorate anions are disordered over two sets of sites with occup...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089310/ https://www.ncbi.nlm.nih.gov/pubmed/21754563 http://dx.doi.org/10.1107/S1600536811015625 |
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author | Türkyılmaz, Murat Baran, Yakup Özdemir, Namık |
author_facet | Türkyılmaz, Murat Baran, Yakup Özdemir, Namık |
author_sort | Türkyılmaz, Murat |
collection | PubMed |
description | In the title molecular salt, C(17)H(17)N(5) (+)·2ClO(4) (−), the dihedral angles between the fused-ring system and the pendant five- and six-membered heterocyclic rings are 6.4 (2) and 41.29 (19)°, respectively. The O atoms of both perchlorate anions are disordered over two sets of sites with occupancy ratios of 0.614 (8):0.386 (8) and 0.591 (7):0.409 (7). An intramolecular C—H⋯N contact occurs in the cation. In the crystal, the components are linked by N—H⋯O and C—H⋯O hydrogen bonds and π–π stacking interactions [centroid–centroid separation = 3.642 (3) Å]. |
format | Text |
id | pubmed-3089310 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30893102011-07-13 2-[2-(1H-Imidazol-3-ium-5-yl)ethyl]-3-(pyridin-2-yl)-2H-imidazo[1,5-a]pyridin-4-ium bis(perchlorate) Türkyılmaz, Murat Baran, Yakup Özdemir, Namık Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecular salt, C(17)H(17)N(5) (+)·2ClO(4) (−), the dihedral angles between the fused-ring system and the pendant five- and six-membered heterocyclic rings are 6.4 (2) and 41.29 (19)°, respectively. The O atoms of both perchlorate anions are disordered over two sets of sites with occupancy ratios of 0.614 (8):0.386 (8) and 0.591 (7):0.409 (7). An intramolecular C—H⋯N contact occurs in the cation. In the crystal, the components are linked by N—H⋯O and C—H⋯O hydrogen bonds and π–π stacking interactions [centroid–centroid separation = 3.642 (3) Å]. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089310/ /pubmed/21754563 http://dx.doi.org/10.1107/S1600536811015625 Text en © Türkyılmaz et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Türkyılmaz, Murat Baran, Yakup Özdemir, Namık 2-[2-(1H-Imidazol-3-ium-5-yl)ethyl]-3-(pyridin-2-yl)-2H-imidazo[1,5-a]pyridin-4-ium bis(perchlorate) |
title | 2-[2-(1H-Imidazol-3-ium-5-yl)ethyl]-3-(pyridin-2-yl)-2H-imidazo[1,5-a]pyridin-4-ium bis(perchlorate) |
title_full | 2-[2-(1H-Imidazol-3-ium-5-yl)ethyl]-3-(pyridin-2-yl)-2H-imidazo[1,5-a]pyridin-4-ium bis(perchlorate) |
title_fullStr | 2-[2-(1H-Imidazol-3-ium-5-yl)ethyl]-3-(pyridin-2-yl)-2H-imidazo[1,5-a]pyridin-4-ium bis(perchlorate) |
title_full_unstemmed | 2-[2-(1H-Imidazol-3-ium-5-yl)ethyl]-3-(pyridin-2-yl)-2H-imidazo[1,5-a]pyridin-4-ium bis(perchlorate) |
title_short | 2-[2-(1H-Imidazol-3-ium-5-yl)ethyl]-3-(pyridin-2-yl)-2H-imidazo[1,5-a]pyridin-4-ium bis(perchlorate) |
title_sort | 2-[2-(1h-imidazol-3-ium-5-yl)ethyl]-3-(pyridin-2-yl)-2h-imidazo[1,5-a]pyridin-4-ium bis(perchlorate) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089310/ https://www.ncbi.nlm.nih.gov/pubmed/21754563 http://dx.doi.org/10.1107/S1600536811015625 |
work_keys_str_mv | AT turkyılmazmurat 221himidazol3ium5ylethyl3pyridin2yl2himidazo15apyridin4iumbisperchlorate AT baranyakup 221himidazol3ium5ylethyl3pyridin2yl2himidazo15apyridin4iumbisperchlorate AT ozdemirnamık 221himidazol3ium5ylethyl3pyridin2yl2himidazo15apyridin4iumbisperchlorate |