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Poly[aqua­bis­(μ-formato-κ(2) O:O′)(μ-pyrazine-κ(2) N:N′)nickel(II)]

In the title compound, [Ni(CHO(2))(2)(C(4)H(4)N(2))(H(2)O)], the nickel(II) cations are coordinated by three O-bonded-formato anions, two N-bonded-pyrazine ligands and one water mol­ecule in an octa­hedral coordination mode. The nickel(II) cations are connected by μ-1,3-bridging formato anions and N...

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Detalles Bibliográficos
Autores principales: Wöhlert, Susanne, Wriedt, Mario, Jess, Inke, Näther, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089312/
https://www.ncbi.nlm.nih.gov/pubmed/21754272
http://dx.doi.org/10.1107/S1600536811011913
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author Wöhlert, Susanne
Wriedt, Mario
Jess, Inke
Näther, Christian
author_facet Wöhlert, Susanne
Wriedt, Mario
Jess, Inke
Näther, Christian
author_sort Wöhlert, Susanne
collection PubMed
description In the title compound, [Ni(CHO(2))(2)(C(4)H(4)N(2))(H(2)O)], the nickel(II) cations are coordinated by three O-bonded-formato anions, two N-bonded-pyrazine ligands and one water mol­ecule in an octa­hedral coordination mode. The nickel(II) cations are connected by μ-1,3-bridging formato anions and N,N′-bridging pyrazine ligands into a three dimensional coordination network. The asymmetric unit consists of one nickel(II) cation, one water mol­ecule and two crystallograph­ically independent formato anions in general positions as well as two crystallographically independent pyrazine ligands, which are located on centers of inversion.
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spelling pubmed-30893122011-07-13 Poly[aqua­bis­(μ-formato-κ(2) O:O′)(μ-pyrazine-κ(2) N:N′)nickel(II)] Wöhlert, Susanne Wriedt, Mario Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(CHO(2))(2)(C(4)H(4)N(2))(H(2)O)], the nickel(II) cations are coordinated by three O-bonded-formato anions, two N-bonded-pyrazine ligands and one water mol­ecule in an octa­hedral coordination mode. The nickel(II) cations are connected by μ-1,3-bridging formato anions and N,N′-bridging pyrazine ligands into a three dimensional coordination network. The asymmetric unit consists of one nickel(II) cation, one water mol­ecule and two crystallograph­ically independent formato anions in general positions as well as two crystallographically independent pyrazine ligands, which are located on centers of inversion. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089312/ /pubmed/21754272 http://dx.doi.org/10.1107/S1600536811011913 Text en © Wöhlert et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wöhlert, Susanne
Wriedt, Mario
Jess, Inke
Näther, Christian
Poly[aqua­bis­(μ-formato-κ(2) O:O′)(μ-pyrazine-κ(2) N:N′)nickel(II)]
title Poly[aqua­bis­(μ-formato-κ(2) O:O′)(μ-pyrazine-κ(2) N:N′)nickel(II)]
title_full Poly[aqua­bis­(μ-formato-κ(2) O:O′)(μ-pyrazine-κ(2) N:N′)nickel(II)]
title_fullStr Poly[aqua­bis­(μ-formato-κ(2) O:O′)(μ-pyrazine-κ(2) N:N′)nickel(II)]
title_full_unstemmed Poly[aqua­bis­(μ-formato-κ(2) O:O′)(μ-pyrazine-κ(2) N:N′)nickel(II)]
title_short Poly[aqua­bis­(μ-formato-κ(2) O:O′)(μ-pyrazine-κ(2) N:N′)nickel(II)]
title_sort poly[aqua­bis­(μ-formato-κ(2) o:o′)(μ-pyrazine-κ(2) n:n′)nickel(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089312/
https://www.ncbi.nlm.nih.gov/pubmed/21754272
http://dx.doi.org/10.1107/S1600536811011913
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