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Poly[aquabis(μ-formato-κ(2) O:O′)(μ-pyrazine-κ(2) N:N′)nickel(II)]
In the title compound, [Ni(CHO(2))(2)(C(4)H(4)N(2))(H(2)O)], the nickel(II) cations are coordinated by three O-bonded-formato anions, two N-bonded-pyrazine ligands and one water molecule in an octahedral coordination mode. The nickel(II) cations are connected by μ-1,3-bridging formato anions and N...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089312/ https://www.ncbi.nlm.nih.gov/pubmed/21754272 http://dx.doi.org/10.1107/S1600536811011913 |
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author | Wöhlert, Susanne Wriedt, Mario Jess, Inke Näther, Christian |
author_facet | Wöhlert, Susanne Wriedt, Mario Jess, Inke Näther, Christian |
author_sort | Wöhlert, Susanne |
collection | PubMed |
description | In the title compound, [Ni(CHO(2))(2)(C(4)H(4)N(2))(H(2)O)], the nickel(II) cations are coordinated by three O-bonded-formato anions, two N-bonded-pyrazine ligands and one water molecule in an octahedral coordination mode. The nickel(II) cations are connected by μ-1,3-bridging formato anions and N,N′-bridging pyrazine ligands into a three dimensional coordination network. The asymmetric unit consists of one nickel(II) cation, one water molecule and two crystallographically independent formato anions in general positions as well as two crystallographically independent pyrazine ligands, which are located on centers of inversion. |
format | Text |
id | pubmed-3089312 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30893122011-07-13 Poly[aquabis(μ-formato-κ(2) O:O′)(μ-pyrazine-κ(2) N:N′)nickel(II)] Wöhlert, Susanne Wriedt, Mario Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(CHO(2))(2)(C(4)H(4)N(2))(H(2)O)], the nickel(II) cations are coordinated by three O-bonded-formato anions, two N-bonded-pyrazine ligands and one water molecule in an octahedral coordination mode. The nickel(II) cations are connected by μ-1,3-bridging formato anions and N,N′-bridging pyrazine ligands into a three dimensional coordination network. The asymmetric unit consists of one nickel(II) cation, one water molecule and two crystallographically independent formato anions in general positions as well as two crystallographically independent pyrazine ligands, which are located on centers of inversion. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089312/ /pubmed/21754272 http://dx.doi.org/10.1107/S1600536811011913 Text en © Wöhlert et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wöhlert, Susanne Wriedt, Mario Jess, Inke Näther, Christian Poly[aquabis(μ-formato-κ(2) O:O′)(μ-pyrazine-κ(2) N:N′)nickel(II)] |
title | Poly[aquabis(μ-formato-κ(2)
O:O′)(μ-pyrazine-κ(2)
N:N′)nickel(II)] |
title_full | Poly[aquabis(μ-formato-κ(2)
O:O′)(μ-pyrazine-κ(2)
N:N′)nickel(II)] |
title_fullStr | Poly[aquabis(μ-formato-κ(2)
O:O′)(μ-pyrazine-κ(2)
N:N′)nickel(II)] |
title_full_unstemmed | Poly[aquabis(μ-formato-κ(2)
O:O′)(μ-pyrazine-κ(2)
N:N′)nickel(II)] |
title_short | Poly[aquabis(μ-formato-κ(2)
O:O′)(μ-pyrazine-κ(2)
N:N′)nickel(II)] |
title_sort | poly[aquabis(μ-formato-κ(2)
o:o′)(μ-pyrazine-κ(2)
n:n′)nickel(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089312/ https://www.ncbi.nlm.nih.gov/pubmed/21754272 http://dx.doi.org/10.1107/S1600536811011913 |
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