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Bis{μ(3)-cis-N-(2-carboxyl­ato-5-chloro­phen­yl)-N′-[3-(dimethyl­amino)­prop­yl]oxamidato(3−)}bis­(perchlorato-κO)bis­(N,N,N′,N′-tetra­methyl­ethylene­diamine)­tetra­copper(II)

The title complex, [Cu(4)(C(14)H(15)ClN(3)O(4))(2)(ClO(4))(2)(C(6)H(16)N(2))(2)], is a tetra­nuclear copper(II) complex lying about an inversion center wherein a cis-oxamide group is coordinated to both Cu atoms with bite angles of 84.45 (6) and 84.08 (10)°. Both Cu atoms adopt distorted square-pyra...

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Detalles Bibliográficos
Autores principales: Sun, Yanlong, Xu, Xuelian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089313/
https://www.ncbi.nlm.nih.gov/pubmed/21754352
http://dx.doi.org/10.1107/S1600536811014978
Descripción
Sumario:The title complex, [Cu(4)(C(14)H(15)ClN(3)O(4))(2)(ClO(4))(2)(C(6)H(16)N(2))(2)], is a tetra­nuclear copper(II) complex lying about an inversion center wherein a cis-oxamide group is coordinated to both Cu atoms with bite angles of 84.45 (6) and 84.08 (10)°. Both Cu atoms adopt distorted square-pyramidal coordination geometries. The apical position of one Cu atom is occupied by an O atom from a perchlorate group, with a Cu—O bond length of 2.519 (7) Å, while the apical site of the other Cu atom is occupied by a carboxyl­ate O atom with a Cu—O distance of 2.281 (3) Å. The Cu atoms bridged by oxamide and carboxyl­ate-group bridges are separated by 5.204 (6) and 5.603 (2) Å, respectively. The crystal structure is consolidated by weak inter­molecular C—H⋯O inter­actions. Two perchlorate O atoms are disordered with unequal site-occupancy factors.