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Bis{μ(3)-cis-N-(2-carboxylato-5-chlorophenyl)-N′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato-κO)bis(N,N,N′,N′-tetramethylethylenediamine)tetracopper(II)
The title complex, [Cu(4)(C(14)H(15)ClN(3)O(4))(2)(ClO(4))(2)(C(6)H(16)N(2))(2)], is a tetranuclear copper(II) complex lying about an inversion center wherein a cis-oxamide group is coordinated to both Cu atoms with bite angles of 84.45 (6) and 84.08 (10)°. Both Cu atoms adopt distorted square-pyra...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089313/ https://www.ncbi.nlm.nih.gov/pubmed/21754352 http://dx.doi.org/10.1107/S1600536811014978 |
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author | Sun, Yanlong Xu, Xuelian |
author_facet | Sun, Yanlong Xu, Xuelian |
author_sort | Sun, Yanlong |
collection | PubMed |
description | The title complex, [Cu(4)(C(14)H(15)ClN(3)O(4))(2)(ClO(4))(2)(C(6)H(16)N(2))(2)], is a tetranuclear copper(II) complex lying about an inversion center wherein a cis-oxamide group is coordinated to both Cu atoms with bite angles of 84.45 (6) and 84.08 (10)°. Both Cu atoms adopt distorted square-pyramidal coordination geometries. The apical position of one Cu atom is occupied by an O atom from a perchlorate group, with a Cu—O bond length of 2.519 (7) Å, while the apical site of the other Cu atom is occupied by a carboxylate O atom with a Cu—O distance of 2.281 (3) Å. The Cu atoms bridged by oxamide and carboxylate-group bridges are separated by 5.204 (6) and 5.603 (2) Å, respectively. The crystal structure is consolidated by weak intermolecular C—H⋯O interactions. Two perchlorate O atoms are disordered with unequal site-occupancy factors. |
format | Text |
id | pubmed-3089313 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30893132011-07-13 Bis{μ(3)-cis-N-(2-carboxylato-5-chlorophenyl)-N′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato-κO)bis(N,N,N′,N′-tetramethylethylenediamine)tetracopper(II) Sun, Yanlong Xu, Xuelian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(4)(C(14)H(15)ClN(3)O(4))(2)(ClO(4))(2)(C(6)H(16)N(2))(2)], is a tetranuclear copper(II) complex lying about an inversion center wherein a cis-oxamide group is coordinated to both Cu atoms with bite angles of 84.45 (6) and 84.08 (10)°. Both Cu atoms adopt distorted square-pyramidal coordination geometries. The apical position of one Cu atom is occupied by an O atom from a perchlorate group, with a Cu—O bond length of 2.519 (7) Å, while the apical site of the other Cu atom is occupied by a carboxylate O atom with a Cu—O distance of 2.281 (3) Å. The Cu atoms bridged by oxamide and carboxylate-group bridges are separated by 5.204 (6) and 5.603 (2) Å, respectively. The crystal structure is consolidated by weak intermolecular C—H⋯O interactions. Two perchlorate O atoms are disordered with unequal site-occupancy factors. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089313/ /pubmed/21754352 http://dx.doi.org/10.1107/S1600536811014978 Text en © Sun and Xu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sun, Yanlong Xu, Xuelian Bis{μ(3)-cis-N-(2-carboxylato-5-chlorophenyl)-N′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato-κO)bis(N,N,N′,N′-tetramethylethylenediamine)tetracopper(II) |
title | Bis{μ(3)-cis-N-(2-carboxylato-5-chlorophenyl)-N′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato-κO)bis(N,N,N′,N′-tetramethylethylenediamine)tetracopper(II) |
title_full | Bis{μ(3)-cis-N-(2-carboxylato-5-chlorophenyl)-N′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato-κO)bis(N,N,N′,N′-tetramethylethylenediamine)tetracopper(II) |
title_fullStr | Bis{μ(3)-cis-N-(2-carboxylato-5-chlorophenyl)-N′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato-κO)bis(N,N,N′,N′-tetramethylethylenediamine)tetracopper(II) |
title_full_unstemmed | Bis{μ(3)-cis-N-(2-carboxylato-5-chlorophenyl)-N′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato-κO)bis(N,N,N′,N′-tetramethylethylenediamine)tetracopper(II) |
title_short | Bis{μ(3)-cis-N-(2-carboxylato-5-chlorophenyl)-N′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato-κO)bis(N,N,N′,N′-tetramethylethylenediamine)tetracopper(II) |
title_sort | bis{μ(3)-cis-n-(2-carboxylato-5-chlorophenyl)-n′-[3-(dimethylamino)propyl]oxamidato(3−)}bis(perchlorato-κo)bis(n,n,n′,n′-tetramethylethylenediamine)tetracopper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089313/ https://www.ncbi.nlm.nih.gov/pubmed/21754352 http://dx.doi.org/10.1107/S1600536811014978 |
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