rac-2,2′-(Thiane-2,6-di­yl)bis­[1-(4-bromo­phen­yl)ethanone]

In the title compound, C(21)H(20)Br(2)O(2)S, prepared by the reaction of 1,9-bis­(4-bromo­phen­yl)nona-2,7-diene-1,9-dione with sodium sulfide nona­hydrate in acetonitrile, the six-membered thio­pyran ring has a chair conformation while the H atoms ortho to the S atom adopt a cis configuration. The...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Li-Qiang, Yang, Jing-Kui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089314/
https://www.ncbi.nlm.nih.gov/pubmed/21754374
http://dx.doi.org/10.1107/S1600536811011792
_version_ 1782203028222246912
author Liu, Li-Qiang
Yang, Jing-Kui
author_facet Liu, Li-Qiang
Yang, Jing-Kui
author_sort Liu, Li-Qiang
collection PubMed
description In the title compound, C(21)H(20)Br(2)O(2)S, prepared by the reaction of 1,9-bis­(4-bromo­phen­yl)nona-2,7-diene-1,9-dione with sodium sulfide nona­hydrate in acetonitrile, the six-membered thio­pyran ring has a chair conformation while the H atoms ortho to the S atom adopt a cis configuration. The dihedral angle between the two benzene rings is 2.59 (8)°.
format Text
id pubmed-3089314
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30893142011-07-13 rac-2,2′-(Thiane-2,6-di­yl)bis­[1-(4-bromo­phen­yl)ethanone] Liu, Li-Qiang Yang, Jing-Kui Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(20)Br(2)O(2)S, prepared by the reaction of 1,9-bis­(4-bromo­phen­yl)nona-2,7-diene-1,9-dione with sodium sulfide nona­hydrate in acetonitrile, the six-membered thio­pyran ring has a chair conformation while the H atoms ortho to the S atom adopt a cis configuration. The dihedral angle between the two benzene rings is 2.59 (8)°. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089314/ /pubmed/21754374 http://dx.doi.org/10.1107/S1600536811011792 Text en © Liu and Yang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Li-Qiang
Yang, Jing-Kui
rac-2,2′-(Thiane-2,6-di­yl)bis­[1-(4-bromo­phen­yl)ethanone]
title rac-2,2′-(Thiane-2,6-di­yl)bis­[1-(4-bromo­phen­yl)ethanone]
title_full rac-2,2′-(Thiane-2,6-di­yl)bis­[1-(4-bromo­phen­yl)ethanone]
title_fullStr rac-2,2′-(Thiane-2,6-di­yl)bis­[1-(4-bromo­phen­yl)ethanone]
title_full_unstemmed rac-2,2′-(Thiane-2,6-di­yl)bis­[1-(4-bromo­phen­yl)ethanone]
title_short rac-2,2′-(Thiane-2,6-di­yl)bis­[1-(4-bromo­phen­yl)ethanone]
title_sort rac-2,2′-(thiane-2,6-di­yl)bis­[1-(4-bromo­phen­yl)ethanone]
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089314/
https://www.ncbi.nlm.nih.gov/pubmed/21754374
http://dx.doi.org/10.1107/S1600536811011792
work_keys_str_mv AT liuliqiang rac22thiane26diylbis14bromophenylethanone
AT yangjingkui rac22thiane26diylbis14bromophenylethanone

Ejemplares similares