Bis(pyridazine-κN)bis­(seleno­cyanato-κN)zinc

The asymmetric unit of the title compound, [Zn(NCSe)(2)(C(4)H(4)N(2))(2)], consists of one Zn(II) cation, located on a twofold rotation axis, one seleno­cyanate anion and one pyridazine ligand in general positions. The Zn(II) atom is coordinated by two N-atoms of two pyridazine ligands and two termi...

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Detalles Bibliográficos
Autores principales: Reinert, Thorben, Boeckmann, Jan, Näther, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089317/
https://www.ncbi.nlm.nih.gov/pubmed/21754297
http://dx.doi.org/10.1107/S1600536811012621
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author Reinert, Thorben
Boeckmann, Jan
Näther, Christian
author_facet Reinert, Thorben
Boeckmann, Jan
Näther, Christian
author_sort Reinert, Thorben
collection PubMed
description The asymmetric unit of the title compound, [Zn(NCSe)(2)(C(4)H(4)N(2))(2)], consists of one Zn(II) cation, located on a twofold rotation axis, one seleno­cyanate anion and one pyridazine ligand in general positions. The Zn(II) atom is coordinated by two N-atoms of two pyridazine ligands and two terminal N-bonded seleno­cyanate anions within a slightly distorted tetra­hedral coordination environment. In the crystal, discrete complex mol­ecules are arranged in layers parallel to the ac plane, with Zn(II)⋯Zn(II) distances of 8.0906 (6) Å along the a axis and of 9.0490 (7) or 9.3604 (7) Å along the c axis. The complex mol­ecules are further linked via weak Se⋯Se inter­actions, with Se⋯Se distances of 3.8235 (9) Å.
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spelling pubmed-30893172011-07-13 Bis(pyridazine-κN)bis­(seleno­cyanato-κN)zinc Reinert, Thorben Boeckmann, Jan Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Zn(NCSe)(2)(C(4)H(4)N(2))(2)], consists of one Zn(II) cation, located on a twofold rotation axis, one seleno­cyanate anion and one pyridazine ligand in general positions. The Zn(II) atom is coordinated by two N-atoms of two pyridazine ligands and two terminal N-bonded seleno­cyanate anions within a slightly distorted tetra­hedral coordination environment. In the crystal, discrete complex mol­ecules are arranged in layers parallel to the ac plane, with Zn(II)⋯Zn(II) distances of 8.0906 (6) Å along the a axis and of 9.0490 (7) or 9.3604 (7) Å along the c axis. The complex mol­ecules are further linked via weak Se⋯Se inter­actions, with Se⋯Se distances of 3.8235 (9) Å. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089317/ /pubmed/21754297 http://dx.doi.org/10.1107/S1600536811012621 Text en © Reinert et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Reinert, Thorben
Boeckmann, Jan
Näther, Christian
Bis(pyridazine-κN)bis­(seleno­cyanato-κN)zinc
title Bis(pyridazine-κN)bis­(seleno­cyanato-κN)zinc
title_full Bis(pyridazine-κN)bis­(seleno­cyanato-κN)zinc
title_fullStr Bis(pyridazine-κN)bis­(seleno­cyanato-κN)zinc
title_full_unstemmed Bis(pyridazine-κN)bis­(seleno­cyanato-κN)zinc
title_short Bis(pyridazine-κN)bis­(seleno­cyanato-κN)zinc
title_sort bis(pyridazine-κn)bis­(seleno­cyanato-κn)zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089317/
https://www.ncbi.nlm.nih.gov/pubmed/21754297
http://dx.doi.org/10.1107/S1600536811012621
work_keys_str_mv AT reinertthorben bispyridazineknbisselenocyanatoknzinc
AT boeckmannjan bispyridazineknbisselenocyanatoknzinc
AT natherchristian bispyridazineknbisselenocyanatoknzinc

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