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[1,2-Bis(pyridin-2-ylmethoxy)benzene-κ(4) N,O,O′,N′]dichloridocopper(II)
In the title compound, [CuCl(2)(C(18)H(16)N(2)O(2))], the Cu(II) atom lies on a twofold axis and is six-coordinated in a distorted octahedral environment defined by two N and two O atoms from the ligand and by two Cl atoms. In the crystal, π–π interactions [centroid–centroid distance = 3.838 (1) Å...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089321/ https://www.ncbi.nlm.nih.gov/pubmed/21754316 http://dx.doi.org/10.1107/S160053681101333X |
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author | Huang, Nan-Nan Zhang, Shuang Liu, Ying Hou, Guang-Feng Gao, Jin-Sheng |
author_facet | Huang, Nan-Nan Zhang, Shuang Liu, Ying Hou, Guang-Feng Gao, Jin-Sheng |
author_sort | Huang, Nan-Nan |
collection | PubMed |
description | In the title compound, [CuCl(2)(C(18)H(16)N(2)O(2))], the Cu(II) atom lies on a twofold axis and is six-coordinated in a distorted octahedral environment defined by two N and two O atoms from the ligand and by two Cl atoms. In the crystal, π–π interactions [centroid–centroid distance = 3.838 (1) Å] and C—H⋯Cl hydrogen bonds link adjacent molecules into a chain structure along [101]. |
format | Text |
id | pubmed-3089321 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30893212011-07-13 [1,2-Bis(pyridin-2-ylmethoxy)benzene-κ(4) N,O,O′,N′]dichloridocopper(II) Huang, Nan-Nan Zhang, Shuang Liu, Ying Hou, Guang-Feng Gao, Jin-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuCl(2)(C(18)H(16)N(2)O(2))], the Cu(II) atom lies on a twofold axis and is six-coordinated in a distorted octahedral environment defined by two N and two O atoms from the ligand and by two Cl atoms. In the crystal, π–π interactions [centroid–centroid distance = 3.838 (1) Å] and C—H⋯Cl hydrogen bonds link adjacent molecules into a chain structure along [101]. International Union of Crystallography 2011-04-16 /pmc/articles/PMC3089321/ /pubmed/21754316 http://dx.doi.org/10.1107/S160053681101333X Text en © Huang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Huang, Nan-Nan Zhang, Shuang Liu, Ying Hou, Guang-Feng Gao, Jin-Sheng [1,2-Bis(pyridin-2-ylmethoxy)benzene-κ(4) N,O,O′,N′]dichloridocopper(II) |
title | [1,2-Bis(pyridin-2-ylmethoxy)benzene-κ(4)
N,O,O′,N′]dichloridocopper(II) |
title_full | [1,2-Bis(pyridin-2-ylmethoxy)benzene-κ(4)
N,O,O′,N′]dichloridocopper(II) |
title_fullStr | [1,2-Bis(pyridin-2-ylmethoxy)benzene-κ(4)
N,O,O′,N′]dichloridocopper(II) |
title_full_unstemmed | [1,2-Bis(pyridin-2-ylmethoxy)benzene-κ(4)
N,O,O′,N′]dichloridocopper(II) |
title_short | [1,2-Bis(pyridin-2-ylmethoxy)benzene-κ(4)
N,O,O′,N′]dichloridocopper(II) |
title_sort | [1,2-bis(pyridin-2-ylmethoxy)benzene-κ(4)
n,o,o′,n′]dichloridocopper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089321/ https://www.ncbi.nlm.nih.gov/pubmed/21754316 http://dx.doi.org/10.1107/S160053681101333X |
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