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rac-Ethyl (2Z)-3-{2-[(Z)-4-ethoxy-4-oxobut-2-en-2-ylamino]cyclohexylamino}but-2-enoate
The asymmetric unit of the title compound, C(18)H(30)N(2)O(4), contains two independent molecules. In each molecule, the cyclohexane ring adopts a chair conformation with equatorial orientation of the substituents, and the conformation is stabilized by two intramolecular N—H⋯O hydrogen bonds, fo...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089325/ https://www.ncbi.nlm.nih.gov/pubmed/21754555 http://dx.doi.org/10.1107/S1600536811015248 |
Sumario: | The asymmetric unit of the title compound, C(18)H(30)N(2)O(4), contains two independent molecules. In each molecule, the cyclohexane ring adopts a chair conformation with equatorial orientation of the substituents, and the conformation is stabilized by two intramolecular N—H⋯O hydrogen bonds, forming rings of S(6) graph-set motif. One ethoxy group and one ethyl group are disordered over two sets of sites with refined occupancy ratios of 0.704 (2):0.296 (2) and 0.505 (3):0.495 (3), respectively. In the crystal, a weak intermolecular C—H⋯O hydrogen interaction is observed, involving the O atom of the major component of the disordered ethoxy group. |
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