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Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)]
In the title complex, [CoK(2)(C(3)H(2)O(4))(2)(H(2)O)(4)](n), the Co atom is located on a position with site symmetry 2/m, the K atom and one water molecule are located on a mirror plane, and the malonate and one water molecule are located on a twofold rotation axis. The K(I) atom is seven-coordin...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089327/ https://www.ncbi.nlm.nih.gov/pubmed/21754320 http://dx.doi.org/10.1107/S1600536811012839 |
Sumario: | In the title complex, [CoK(2)(C(3)H(2)O(4))(2)(H(2)O)(4)](n), the Co atom is located on a position with site symmetry 2/m, the K atom and one water molecule are located on a mirror plane, and the malonate and one water molecule are located on a twofold rotation axis. The K(I) atom is seven-coordinated by four carboxylate O atoms from four malonate ligands and by three water O atoms, forming a distorted polyhedron. The Co(II) atom is in an almost octahedral environment formed by four carboxylate O atoms from two malonate ligands and two water O atoms. The structure consists of layers parallel to (20[Image: see text]) built up from edge-sharing KO(7) and CoO(6) polyhedra, which are connected by O—H⋯O hydrogen bonding including water molecules into a three-dimensional network. |
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