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Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)]
In the title complex, [CoK(2)(C(3)H(2)O(4))(2)(H(2)O)(4)](n), the Co atom is located on a position with site symmetry 2/m, the K atom and one water molecule are located on a mirror plane, and the malonate and one water molecule are located on a twofold rotation axis. The K(I) atom is seven-coordin...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089327/ https://www.ncbi.nlm.nih.gov/pubmed/21754320 http://dx.doi.org/10.1107/S1600536811012839 |
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author | Sy, Adama Barry, Aliou Hamady Gaye, Mohamed Sall, Abdou Salam Driss, Ahmed |
author_facet | Sy, Adama Barry, Aliou Hamady Gaye, Mohamed Sall, Abdou Salam Driss, Ahmed |
author_sort | Sy, Adama |
collection | PubMed |
description | In the title complex, [CoK(2)(C(3)H(2)O(4))(2)(H(2)O)(4)](n), the Co atom is located on a position with site symmetry 2/m, the K atom and one water molecule are located on a mirror plane, and the malonate and one water molecule are located on a twofold rotation axis. The K(I) atom is seven-coordinated by four carboxylate O atoms from four malonate ligands and by three water O atoms, forming a distorted polyhedron. The Co(II) atom is in an almost octahedral environment formed by four carboxylate O atoms from two malonate ligands and two water O atoms. The structure consists of layers parallel to (20[Image: see text]) built up from edge-sharing KO(7) and CoO(6) polyhedra, which are connected by O—H⋯O hydrogen bonding including water molecules into a three-dimensional network. |
format | Text |
id | pubmed-3089327 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30893272011-07-13 Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)] Sy, Adama Barry, Aliou Hamady Gaye, Mohamed Sall, Abdou Salam Driss, Ahmed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CoK(2)(C(3)H(2)O(4))(2)(H(2)O)(4)](n), the Co atom is located on a position with site symmetry 2/m, the K atom and one water molecule are located on a mirror plane, and the malonate and one water molecule are located on a twofold rotation axis. The K(I) atom is seven-coordinated by four carboxylate O atoms from four malonate ligands and by three water O atoms, forming a distorted polyhedron. The Co(II) atom is in an almost octahedral environment formed by four carboxylate O atoms from two malonate ligands and two water O atoms. The structure consists of layers parallel to (20[Image: see text]) built up from edge-sharing KO(7) and CoO(6) polyhedra, which are connected by O—H⋯O hydrogen bonding including water molecules into a three-dimensional network. International Union of Crystallography 2011-04-16 /pmc/articles/PMC3089327/ /pubmed/21754320 http://dx.doi.org/10.1107/S1600536811012839 Text en © Sy et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sy, Adama Barry, Aliou Hamady Gaye, Mohamed Sall, Abdou Salam Driss, Ahmed Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)] |
title | Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)] |
title_full | Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)] |
title_fullStr | Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)] |
title_full_unstemmed | Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)] |
title_short | Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)] |
title_sort | poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(ii)dipotassium(i)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089327/ https://www.ncbi.nlm.nih.gov/pubmed/21754320 http://dx.doi.org/10.1107/S1600536811012839 |
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