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Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)]

In the title complex, [CoK(2)(C(3)H(2)O(4))(2)(H(2)O)(4)](n), the Co atom is located on a position with site symmetry 2/m, the K atom and one water mol­ecule are located on a mirror plane, and the malonate and one water mol­ecule are located on a twofold rotation axis. The K(I) atom is seven-coordin...

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Detalles Bibliográficos
Autores principales: Sy, Adama, Barry, Aliou Hamady, Gaye, Mohamed, Sall, Abdou Salam, Driss, Ahmed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089327/
https://www.ncbi.nlm.nih.gov/pubmed/21754320
http://dx.doi.org/10.1107/S1600536811012839
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author Sy, Adama
Barry, Aliou Hamady
Gaye, Mohamed
Sall, Abdou Salam
Driss, Ahmed
author_facet Sy, Adama
Barry, Aliou Hamady
Gaye, Mohamed
Sall, Abdou Salam
Driss, Ahmed
author_sort Sy, Adama
collection PubMed
description In the title complex, [CoK(2)(C(3)H(2)O(4))(2)(H(2)O)(4)](n), the Co atom is located on a position with site symmetry 2/m, the K atom and one water mol­ecule are located on a mirror plane, and the malonate and one water mol­ecule are located on a twofold rotation axis. The K(I) atom is seven-coordinated by four carboxyl­ate O atoms from four malonate ligands and by three water O atoms, forming a distorted polyhedron. The Co(II) atom is in an almost octa­hedral environment formed by four carboxyl­ate O atoms from two malonate ligands and two water O atoms. The structure consists of layers parallel to (20[Image: see text]) built up from edge-sharing KO(7) and CoO(6) polyhedra, which are connected by O—H⋯O hydrogen bonding including water mol­ecules into a three-dimensional network.
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spelling pubmed-30893272011-07-13 Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)] Sy, Adama Barry, Aliou Hamady Gaye, Mohamed Sall, Abdou Salam Driss, Ahmed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CoK(2)(C(3)H(2)O(4))(2)(H(2)O)(4)](n), the Co atom is located on a position with site symmetry 2/m, the K atom and one water mol­ecule are located on a mirror plane, and the malonate and one water mol­ecule are located on a twofold rotation axis. The K(I) atom is seven-coordinated by four carboxyl­ate O atoms from four malonate ligands and by three water O atoms, forming a distorted polyhedron. The Co(II) atom is in an almost octa­hedral environment formed by four carboxyl­ate O atoms from two malonate ligands and two water O atoms. The structure consists of layers parallel to (20[Image: see text]) built up from edge-sharing KO(7) and CoO(6) polyhedra, which are connected by O—H⋯O hydrogen bonding including water mol­ecules into a three-dimensional network. International Union of Crystallography 2011-04-16 /pmc/articles/PMC3089327/ /pubmed/21754320 http://dx.doi.org/10.1107/S1600536811012839 Text en © Sy et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sy, Adama
Barry, Aliou Hamady
Gaye, Mohamed
Sall, Abdou Salam
Driss, Ahmed
Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)]
title Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)]
title_full Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)]
title_fullStr Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)]
title_full_unstemmed Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)]
title_short Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)]
title_sort poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(ii)dipotassium(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089327/
https://www.ncbi.nlm.nih.gov/pubmed/21754320
http://dx.doi.org/10.1107/S1600536811012839
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