Diiodido{2-(morpholin-4-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}zinc

In the title compound, [ZnI(2)(C(13)H(19)N(3)O)], the Zn(II) ion is five-coordinated in a distorted square-pyramidal geometry, in which the basal plane is defined by three N atoms from the Schiff base ligand and one iodide ion. A second iodide ligand, situated in the apical position, completes the c...

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Detalles Bibliográficos
Autores principales: Suleiman Gwaram, Nura, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089331/
https://www.ncbi.nlm.nih.gov/pubmed/21754337
http://dx.doi.org/10.1107/S1600536811014656
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author Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Suleiman Gwaram, Nura
collection PubMed
description In the title compound, [ZnI(2)(C(13)H(19)N(3)O)], the Zn(II) ion is five-coordinated in a distorted square-pyramidal geometry, in which the basal plane is defined by three N atoms from the Schiff base ligand and one iodide ion. A second iodide ligand, situated in the apical position, completes the coordination geometry. In the crystal structure, C—H⋯O hydrogen bonds link a pair of mol­ecules around an inversion centre into a dimer.
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spelling pubmed-30893312011-07-13 Diiodido{2-(morpholin-4-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}zinc Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnI(2)(C(13)H(19)N(3)O)], the Zn(II) ion is five-coordinated in a distorted square-pyramidal geometry, in which the basal plane is defined by three N atoms from the Schiff base ligand and one iodide ion. A second iodide ligand, situated in the apical position, completes the coordination geometry. In the crystal structure, C—H⋯O hydrogen bonds link a pair of mol­ecules around an inversion centre into a dimer. International Union of Crystallography 2011-04-22 /pmc/articles/PMC3089331/ /pubmed/21754337 http://dx.doi.org/10.1107/S1600536811014656 Text en © Suleiman Gwaram et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suleiman Gwaram, Nura
Khaledi, Hamid
Mohd Ali, Hapipah
Diiodido{2-(morpholin-4-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}zinc
title Diiodido{2-(morpholin-4-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}zinc
title_full Diiodido{2-(morpholin-4-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}zinc
title_fullStr Diiodido{2-(morpholin-4-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}zinc
title_full_unstemmed Diiodido{2-(morpholin-4-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}zinc
title_short Diiodido{2-(morpholin-4-yl)-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}zinc
title_sort diiodido{2-(morpholin-4-yl)-n-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) n,n′,n′′}zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089331/
https://www.ncbi.nlm.nih.gov/pubmed/21754337
http://dx.doi.org/10.1107/S1600536811014656
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