(N-Butyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV)

The title compound, [Sn(C(6)H(5))(3)(C(11)H(14)NS(2))], features a tetra­hedrally coordinated Sn atom, as the dithio­carbamate ligand coordinates in a monodentate fashion. Due to the proximity of the non-coordinating thione S atom, distortions from ideal tetra­hedral geometry about the metal atom ar...

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Detalles Bibliográficos
Autores principales: Kamaludin, Nurul Farahana, Baba, Ibrahim, Awang, Normah, Mohamed Tahir, Mohamed Ibrahim, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089335/
https://www.ncbi.nlm.nih.gov/pubmed/21754289
http://dx.doi.org/10.1107/S1600536811012426
Descripción
Sumario:The title compound, [Sn(C(6)H(5))(3)(C(11)H(14)NS(2))], features a tetra­hedrally coordinated Sn atom, as the dithio­carbamate ligand coordinates in a monodentate fashion. Due to the proximity of the non-coordinating thione S atom, distortions from ideal tetra­hedral geometry about the metal atom are evident with the widest C—Sn—S angle being 117.26 (5)°. In the crystal, mol­ecules are linked by C—H⋯S inter­actions, which generate helical supra­molecular chains along the b axis.

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