(N-Butyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV)

The title compound, [Sn(C(6)H(5))(3)(C(11)H(14)NS(2))], features a tetra­hedrally coordinated Sn atom, as the dithio­carbamate ligand coordinates in a monodentate fashion. Due to the proximity of the non-coordinating thione S atom, distortions from ideal tetra­hedral geometry about the metal atom ar...

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Detalles Bibliográficos
Autores principales: Kamaludin, Nurul Farahana, Baba, Ibrahim, Awang, Normah, Mohamed Tahir, Mohamed Ibrahim, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089335/
https://www.ncbi.nlm.nih.gov/pubmed/21754289
http://dx.doi.org/10.1107/S1600536811012426
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author Kamaludin, Nurul Farahana
Baba, Ibrahim
Awang, Normah
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
author_facet Kamaludin, Nurul Farahana
Baba, Ibrahim
Awang, Normah
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
author_sort Kamaludin, Nurul Farahana
collection PubMed
description The title compound, [Sn(C(6)H(5))(3)(C(11)H(14)NS(2))], features a tetra­hedrally coordinated Sn atom, as the dithio­carbamate ligand coordinates in a monodentate fashion. Due to the proximity of the non-coordinating thione S atom, distortions from ideal tetra­hedral geometry about the metal atom are evident with the widest C—Sn—S angle being 117.26 (5)°. In the crystal, mol­ecules are linked by C—H⋯S inter­actions, which generate helical supra­molecular chains along the b axis.
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spelling pubmed-30893352011-07-13 (N-Butyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV) Kamaludin, Nurul Farahana Baba, Ibrahim Awang, Normah Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(C(6)H(5))(3)(C(11)H(14)NS(2))], features a tetra­hedrally coordinated Sn atom, as the dithio­carbamate ligand coordinates in a monodentate fashion. Due to the proximity of the non-coordinating thione S atom, distortions from ideal tetra­hedral geometry about the metal atom are evident with the widest C—Sn—S angle being 117.26 (5)°. In the crystal, mol­ecules are linked by C—H⋯S inter­actions, which generate helical supra­molecular chains along the b axis. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089335/ /pubmed/21754289 http://dx.doi.org/10.1107/S1600536811012426 Text en © Kamaludin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kamaludin, Nurul Farahana
Baba, Ibrahim
Awang, Normah
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
(N-Butyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV)
title (N-Butyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV)
title_full (N-Butyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV)
title_fullStr (N-Butyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV)
title_full_unstemmed (N-Butyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV)
title_short (N-Butyl-N-phenyl­dithio­carbamato-κS)triphenyl­tin(IV)
title_sort (n-butyl-n-phenyl­dithio­carbamato-κs)triphenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089335/
https://www.ncbi.nlm.nih.gov/pubmed/21754289
http://dx.doi.org/10.1107/S1600536811012426
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