N,N-Dibenzoyl­ferrocenecarboxamide

In the title compound, [Fe(C(5)H(5))(C(20)H(14)NO(3))], the cyclo­penta­dienyl rings deviate by 9.3 (2)° from an eclipsed conformation, defined by C—Cg (1)—Cg (2)—C pseudo-torsion angles ranging from 8.8 (1) to 9.85 (1)°. The coordination at the N atom is slightly pyramidal, as indicated by the angu...

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Detalles Bibliográficos
Autores principales: Cetina, Mario, Kovač, Veronika, Rapić, Vladimir
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089337/
https://www.ncbi.nlm.nih.gov/pubmed/21754327
http://dx.doi.org/10.1107/S1600536811013754
Descripción
Sumario:In the title compound, [Fe(C(5)H(5))(C(20)H(14)NO(3))], the cyclo­penta­dienyl rings deviate by 9.3 (2)° from an eclipsed conformation, defined by C—Cg (1)—Cg (2)—C pseudo-torsion angles ranging from 8.8 (1) to 9.85 (1)°. The coordination at the N atom is slightly pyramidal, as indicated by the angular sum around it of 352.6°. The amide group is inclined at 17.86 (9) and 27.27 (11)° with respect to the aromatic rings. In the crystal, mol­ecules are linked by one C—H⋯O hydrogen bond and one C—H⋯π inter­action into a two-dimensional framework parallel to the b axis.

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