N,N-Dibenzoyl­ferrocenecarboxamide

In the title compound, [Fe(C(5)H(5))(C(20)H(14)NO(3))], the cyclo­penta­dienyl rings deviate by 9.3 (2)° from an eclipsed conformation, defined by C—Cg (1)—Cg (2)—C pseudo-torsion angles ranging from 8.8 (1) to 9.85 (1)°. The coordination at the N atom is slightly pyramidal, as indicated by the angu...

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Detalles Bibliográficos
Autores principales: Cetina, Mario, Kovač, Veronika, Rapić, Vladimir
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089337/
https://www.ncbi.nlm.nih.gov/pubmed/21754327
http://dx.doi.org/10.1107/S1600536811013754
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author Cetina, Mario
Kovač, Veronika
Rapić, Vladimir
author_facet Cetina, Mario
Kovač, Veronika
Rapić, Vladimir
author_sort Cetina, Mario
collection PubMed
description In the title compound, [Fe(C(5)H(5))(C(20)H(14)NO(3))], the cyclo­penta­dienyl rings deviate by 9.3 (2)° from an eclipsed conformation, defined by C—Cg (1)—Cg (2)—C pseudo-torsion angles ranging from 8.8 (1) to 9.85 (1)°. The coordination at the N atom is slightly pyramidal, as indicated by the angular sum around it of 352.6°. The amide group is inclined at 17.86 (9) and 27.27 (11)° with respect to the aromatic rings. In the crystal, mol­ecules are linked by one C—H⋯O hydrogen bond and one C—H⋯π inter­action into a two-dimensional framework parallel to the b axis.
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spelling pubmed-30893372011-07-13 N,N-Dibenzoyl­ferrocenecarboxamide Cetina, Mario Kovač, Veronika Rapić, Vladimir Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(20)H(14)NO(3))], the cyclo­penta­dienyl rings deviate by 9.3 (2)° from an eclipsed conformation, defined by C—Cg (1)—Cg (2)—C pseudo-torsion angles ranging from 8.8 (1) to 9.85 (1)°. The coordination at the N atom is slightly pyramidal, as indicated by the angular sum around it of 352.6°. The amide group is inclined at 17.86 (9) and 27.27 (11)° with respect to the aromatic rings. In the crystal, mol­ecules are linked by one C—H⋯O hydrogen bond and one C—H⋯π inter­action into a two-dimensional framework parallel to the b axis. International Union of Crystallography 2011-04-16 /pmc/articles/PMC3089337/ /pubmed/21754327 http://dx.doi.org/10.1107/S1600536811013754 Text en © Cetina et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cetina, Mario
Kovač, Veronika
Rapić, Vladimir
N,N-Dibenzoyl­ferrocenecarboxamide
title N,N-Dibenzoyl­ferrocenecarboxamide
title_full N,N-Dibenzoyl­ferrocenecarboxamide
title_fullStr N,N-Dibenzoyl­ferrocenecarboxamide
title_full_unstemmed N,N-Dibenzoyl­ferrocenecarboxamide
title_short N,N-Dibenzoyl­ferrocenecarboxamide
title_sort n,n-dibenzoyl­ferrocenecarboxamide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089337/
https://www.ncbi.nlm.nih.gov/pubmed/21754327
http://dx.doi.org/10.1107/S1600536811013754
work_keys_str_mv AT cetinamario nndibenzoylferrocenecarboxamide
AT kovacveronika nndibenzoylferrocenecarboxamide
AT rapicvladimir nndibenzoylferrocenecarboxamide

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