Rubidium 2,4,6-trioxo-1,3-diazinan-5-ide–1,3-diazinane-2,4,6-trione–water (1/1/1)

The asymmetric unit of the title compound, Rb(+)·C(4)H(3)N(2)O(3) (−)·C(4)H(4)N(2)O(3)·H(2)O, consists of one rubidium cation, a barbituric acid mol­ecule, a barbiturate anion and one water mol­ecule. The rubidium ion has seven close-contact inter­actions with O atoms, with Rb⋯O distances ranging fr...

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Detalles Bibliográficos
Autores principales: Gryl, Marlena, Stadnicka, Katarzyna
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089342/
https://www.ncbi.nlm.nih.gov/pubmed/21754300
http://dx.doi.org/10.1107/S1600536811012657
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author Gryl, Marlena
Stadnicka, Katarzyna
author_facet Gryl, Marlena
Stadnicka, Katarzyna
author_sort Gryl, Marlena
collection PubMed
description The asymmetric unit of the title compound, Rb(+)·C(4)H(3)N(2)O(3) (−)·C(4)H(4)N(2)O(3)·H(2)O, consists of one rubidium cation, a barbituric acid mol­ecule, a barbiturate anion and one water mol­ecule. The rubidium ion has seven close-contact inter­actions with O atoms, with Rb⋯O distances ranging from 2.8594 (16) to 3.2641 (14) Å. These seven O atoms together with an eighth O atom at 3.492 (2) Å away from Rb form a distorted polyhedron with shape inter­mediate between an anti­prism and a dodeca­hedron. The Rb(+) ions connect layers built of organic components and water mol­ecules linked via N—H⋯O and O—H⋯O hydrogen bonds.
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spelling pubmed-30893422011-07-13 Rubidium 2,4,6-trioxo-1,3-diazinan-5-ide–1,3-diazinane-2,4,6-trione–water (1/1/1) Gryl, Marlena Stadnicka, Katarzyna Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, Rb(+)·C(4)H(3)N(2)O(3) (−)·C(4)H(4)N(2)O(3)·H(2)O, consists of one rubidium cation, a barbituric acid mol­ecule, a barbiturate anion and one water mol­ecule. The rubidium ion has seven close-contact inter­actions with O atoms, with Rb⋯O distances ranging from 2.8594 (16) to 3.2641 (14) Å. These seven O atoms together with an eighth O atom at 3.492 (2) Å away from Rb form a distorted polyhedron with shape inter­mediate between an anti­prism and a dodeca­hedron. The Rb(+) ions connect layers built of organic components and water mol­ecules linked via N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089342/ /pubmed/21754300 http://dx.doi.org/10.1107/S1600536811012657 Text en © Gryl and Stadnicka 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gryl, Marlena
Stadnicka, Katarzyna
Rubidium 2,4,6-trioxo-1,3-diazinan-5-ide–1,3-diazinane-2,4,6-trione–water (1/1/1)
title Rubidium 2,4,6-trioxo-1,3-diazinan-5-ide–1,3-diazinane-2,4,6-trione–water (1/1/1)
title_full Rubidium 2,4,6-trioxo-1,3-diazinan-5-ide–1,3-diazinane-2,4,6-trione–water (1/1/1)
title_fullStr Rubidium 2,4,6-trioxo-1,3-diazinan-5-ide–1,3-diazinane-2,4,6-trione–water (1/1/1)
title_full_unstemmed Rubidium 2,4,6-trioxo-1,3-diazinan-5-ide–1,3-diazinane-2,4,6-trione–water (1/1/1)
title_short Rubidium 2,4,6-trioxo-1,3-diazinan-5-ide–1,3-diazinane-2,4,6-trione–water (1/1/1)
title_sort rubidium 2,4,6-trioxo-1,3-diazinan-5-ide–1,3-diazinane-2,4,6-trione–water (1/1/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089342/
https://www.ncbi.nlm.nih.gov/pubmed/21754300
http://dx.doi.org/10.1107/S1600536811012657
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