6-Bromo-3-{2-[2-(diphenyl­methyl­ene)hydrazin­yl]-1,3-thia­zol-5-yl}-2H-chromen-2-one chloro­form monosolvate

In the title compound, C(25)H(16)BrN(3)O(2)S·CHCl(3), the thia­zole ring is approximately planar [maximum deviation = 0.002 (3) Å] and makes dihedral angles of 10.75 (14) and 87.75 (15)/2.80 (14)° with the pyran ring system and the two terminal phenyl rings, respectively. The solvent mol­ecule is di...

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Autores principales: Arshad, Afsheen, Osman, Hasnah, Lam, Chan Kit, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089344/
https://www.ncbi.nlm.nih.gov/pubmed/21754402
http://dx.doi.org/10.1107/S1600536811012335
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author Arshad, Afsheen
Osman, Hasnah
Lam, Chan Kit
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Arshad, Afsheen
Osman, Hasnah
Lam, Chan Kit
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Arshad, Afsheen
collection PubMed
description In the title compound, C(25)H(16)BrN(3)O(2)S·CHCl(3), the thia­zole ring is approximately planar [maximum deviation = 0.002 (3) Å] and makes dihedral angles of 10.75 (14) and 87.75 (15)/2.80 (14)° with the pyran ring system and the two terminal phenyl rings, respectively. The solvent mol­ecule is disordered over two sets of sites, with refined occupancies of 0.639 (7) and 0.361 (7). In the crystal, mol­ecules are connected via pairs of weak C—H⋯O inter­actions, forming centrosymmetric dimers. An intra­molecular C—H⋯O hydrogen bond generates an S(6) ring motif.
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spelling pubmed-30893442011-07-13 6-Bromo-3-{2-[2-(diphenyl­methyl­ene)hydrazin­yl]-1,3-thia­zol-5-yl}-2H-chromen-2-one chloro­form monosolvate Arshad, Afsheen Osman, Hasnah Lam, Chan Kit Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(16)BrN(3)O(2)S·CHCl(3), the thia­zole ring is approximately planar [maximum deviation = 0.002 (3) Å] and makes dihedral angles of 10.75 (14) and 87.75 (15)/2.80 (14)° with the pyran ring system and the two terminal phenyl rings, respectively. The solvent mol­ecule is disordered over two sets of sites, with refined occupancies of 0.639 (7) and 0.361 (7). In the crystal, mol­ecules are connected via pairs of weak C—H⋯O inter­actions, forming centrosymmetric dimers. An intra­molecular C—H⋯O hydrogen bond generates an S(6) ring motif. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089344/ /pubmed/21754402 http://dx.doi.org/10.1107/S1600536811012335 Text en © Arshad et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arshad, Afsheen
Osman, Hasnah
Lam, Chan Kit
Hemamalini, Madhukar
Fun, Hoong-Kun
6-Bromo-3-{2-[2-(diphenyl­methyl­ene)hydrazin­yl]-1,3-thia­zol-5-yl}-2H-chromen-2-one chloro­form monosolvate
title 6-Bromo-3-{2-[2-(diphenyl­methyl­ene)hydrazin­yl]-1,3-thia­zol-5-yl}-2H-chromen-2-one chloro­form monosolvate
title_full 6-Bromo-3-{2-[2-(diphenyl­methyl­ene)hydrazin­yl]-1,3-thia­zol-5-yl}-2H-chromen-2-one chloro­form monosolvate
title_fullStr 6-Bromo-3-{2-[2-(diphenyl­methyl­ene)hydrazin­yl]-1,3-thia­zol-5-yl}-2H-chromen-2-one chloro­form monosolvate
title_full_unstemmed 6-Bromo-3-{2-[2-(diphenyl­methyl­ene)hydrazin­yl]-1,3-thia­zol-5-yl}-2H-chromen-2-one chloro­form monosolvate
title_short 6-Bromo-3-{2-[2-(diphenyl­methyl­ene)hydrazin­yl]-1,3-thia­zol-5-yl}-2H-chromen-2-one chloro­form monosolvate
title_sort 6-bromo-3-{2-[2-(diphenyl­methyl­ene)hydrazin­yl]-1,3-thia­zol-5-yl}-2h-chromen-2-one chloro­form monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089344/
https://www.ncbi.nlm.nih.gov/pubmed/21754402
http://dx.doi.org/10.1107/S1600536811012335
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AT osmanhasnah 6bromo322diphenylmethylenehydrazinyl13thiazol5yl2hchromen2onechloroformmonosolvate
AT lamchankit 6bromo322diphenylmethylenehydrazinyl13thiazol5yl2hchromen2onechloroformmonosolvate
AT hemamalinimadhukar 6bromo322diphenylmethylenehydrazinyl13thiazol5yl2hchromen2onechloroformmonosolvate
AT funhoongkun 6bromo322diphenylmethylenehydrazinyl13thiazol5yl2hchromen2onechloroformmonosolvate

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