Cargando…
Tetraaquatetrakis{μ(2)-[1-(carboxylatomethyl)cyclohexyl]methanaminium}bis(μ(3)-hydroxido)bis(nitrato-κ(2) O,O′)tetrazinc(II)
As the title gabapentin complex, [Zn(4)(OH)(2)(NO(3))(2)(C(9)H(17)NO(2))(4)(H(2)O)(4)](NO(3))(4) is located about a centre of inversion, the asymmetric unit contains two disordered nitrate ions and half a complex molecule. The two zinc ions have different coordination environments: one is slightly...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089351/ https://www.ncbi.nlm.nih.gov/pubmed/21754301 http://dx.doi.org/10.1107/S1600536811011020 |
Sumario: | As the title gabapentin complex, [Zn(4)(OH)(2)(NO(3))(2)(C(9)H(17)NO(2))(4)(H(2)O)(4)](NO(3))(4) is located about a centre of inversion, the asymmetric unit contains two disordered nitrate ions and half a complex molecule. The two zinc ions have different coordination environments: one is slightly distorted octahedral and the other is trigonal–pyramidal. The conformation of the gabapentin molecule is defined by the formation of two intramolecular O—H⋯O hydrogen bonds. Furthermore, the ammonium H atoms are involved in numerous hydrogen bonds with the disordered nitrate anions. |
---|