Tetraaqua­tetrakis­{μ(2)-[1-(carb­oxylato­meth­yl)cyclo­hex­yl]methanaminium}bis(μ(3)-hydroxido)bis(nitrato-κ(2) O,O′)tetrazinc(II)

As the title gabapentin complex, [Zn(4)(OH)(2)(NO(3))(2)(C(9)H(17)NO(2))(4)(H(2)O)(4)](NO(3))(4) is located about a centre of inversion, the asymmetric unit contains two disordered nitrate ions and half a complex mol­ecule. The two zinc ions have different coordination environments: one is slightly...

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Detalles Bibliográficos
Autores principales: de Vries, Elise J. C., Gamble, Caryn, Shaikjee, Ahmed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089351/
https://www.ncbi.nlm.nih.gov/pubmed/21754301
http://dx.doi.org/10.1107/S1600536811011020
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author de Vries, Elise J. C.
Gamble, Caryn
Shaikjee, Ahmed
author_facet de Vries, Elise J. C.
Gamble, Caryn
Shaikjee, Ahmed
author_sort de Vries, Elise J. C.
collection PubMed
description As the title gabapentin complex, [Zn(4)(OH)(2)(NO(3))(2)(C(9)H(17)NO(2))(4)(H(2)O)(4)](NO(3))(4) is located about a centre of inversion, the asymmetric unit contains two disordered nitrate ions and half a complex mol­ecule. The two zinc ions have different coordination environments: one is slightly distorted octa­hedral and the other is trigonal–pyramidal. The conformation of the gabapentin mol­ecule is defined by the formation of two intra­molecular O—H⋯O hydrogen bonds. Furthermore, the ammonium H atoms are involved in numerous hydrogen bonds with the disordered nitrate anions.
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spelling pubmed-30893512011-07-13 Tetraaqua­tetrakis­{μ(2)-[1-(carb­oxylato­meth­yl)cyclo­hex­yl]methanaminium}bis(μ(3)-hydroxido)bis(nitrato-κ(2) O,O′)tetrazinc(II) de Vries, Elise J. C. Gamble, Caryn Shaikjee, Ahmed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers As the title gabapentin complex, [Zn(4)(OH)(2)(NO(3))(2)(C(9)H(17)NO(2))(4)(H(2)O)(4)](NO(3))(4) is located about a centre of inversion, the asymmetric unit contains two disordered nitrate ions and half a complex mol­ecule. The two zinc ions have different coordination environments: one is slightly distorted octa­hedral and the other is trigonal–pyramidal. The conformation of the gabapentin mol­ecule is defined by the formation of two intra­molecular O—H⋯O hydrogen bonds. Furthermore, the ammonium H atoms are involved in numerous hydrogen bonds with the disordered nitrate anions. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089351/ /pubmed/21754301 http://dx.doi.org/10.1107/S1600536811011020 Text en © Vries et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
de Vries, Elise J. C.
Gamble, Caryn
Shaikjee, Ahmed
Tetraaqua­tetrakis­{μ(2)-[1-(carb­oxylato­meth­yl)cyclo­hex­yl]methanaminium}bis(μ(3)-hydroxido)bis(nitrato-κ(2) O,O′)tetrazinc(II)
title Tetraaqua­tetrakis­{μ(2)-[1-(carb­oxylato­meth­yl)cyclo­hex­yl]methanaminium}bis(μ(3)-hydroxido)bis(nitrato-κ(2) O,O′)tetrazinc(II)
title_full Tetraaqua­tetrakis­{μ(2)-[1-(carb­oxylato­meth­yl)cyclo­hex­yl]methanaminium}bis(μ(3)-hydroxido)bis(nitrato-κ(2) O,O′)tetrazinc(II)
title_fullStr Tetraaqua­tetrakis­{μ(2)-[1-(carb­oxylato­meth­yl)cyclo­hex­yl]methanaminium}bis(μ(3)-hydroxido)bis(nitrato-κ(2) O,O′)tetrazinc(II)
title_full_unstemmed Tetraaqua­tetrakis­{μ(2)-[1-(carb­oxylato­meth­yl)cyclo­hex­yl]methanaminium}bis(μ(3)-hydroxido)bis(nitrato-κ(2) O,O′)tetrazinc(II)
title_short Tetraaqua­tetrakis­{μ(2)-[1-(carb­oxylato­meth­yl)cyclo­hex­yl]methanaminium}bis(μ(3)-hydroxido)bis(nitrato-κ(2) O,O′)tetrazinc(II)
title_sort tetraaqua­tetrakis­{μ(2)-[1-(carb­oxylato­meth­yl)cyclo­hex­yl]methanaminium}bis(μ(3)-hydroxido)bis(nitrato-κ(2) o,o′)tetrazinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089351/
https://www.ncbi.nlm.nih.gov/pubmed/21754301
http://dx.doi.org/10.1107/S1600536811011020
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AT shaikjeeahmed tetraaquatetrakism21carboxylatomethylcyclohexylmethanaminiumbism3hydroxidobisnitratok2ootetrazincii

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