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Dicarbon­yl(η(5)-cyclo­penta­dien­yl)[2-(phenyl­sulfan­yl)eth­yl]iron(II)

The title compound, [Fe(C(5)H(5))(C(8)H(9)S)(CO)(2)], is a three-legged piano-stool iron(II) complex that is characterized by a thio­ethyl-linked phenyl ring and a cyclo­penta­dienyl moiety that occupies the apical coordination site. The two aromatic rings are essentially planar with the same maximu...

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Detalles Bibliográficos
Autores principales: Mkhize, Dennis S., Nyamori, Vincent O., Bala, Muhammad D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089356/
https://www.ncbi.nlm.nih.gov/pubmed/21754351
http://dx.doi.org/10.1107/S160053681101511X
Descripción
Sumario:The title compound, [Fe(C(5)H(5))(C(8)H(9)S)(CO)(2)], is a three-legged piano-stool iron(II) complex that is characterized by a thio­ethyl-linked phenyl ring and a cyclo­penta­dienyl moiety that occupies the apical coordination site. The two aromatic rings are essentially planar with the same maximum deviation of 0.009 Å. The mean planes of the phenyl and cyclo­penta­dienyl rings bis­ect at an acute angle of 50.08°.