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Dicarbonyl(η(5)-cyclopentadienyl)[2-(phenylsulfanyl)ethyl]iron(II)
The title compound, [Fe(C(5)H(5))(C(8)H(9)S)(CO)(2)], is a three-legged piano-stool iron(II) complex that is characterized by a thioethyl-linked phenyl ring and a cyclopentadienyl moiety that occupies the apical coordination site. The two aromatic rings are essentially planar with the same maximu...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089356/ https://www.ncbi.nlm.nih.gov/pubmed/21754351 http://dx.doi.org/10.1107/S160053681101511X |
| _version_ | 1782203038277042176 |
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| author | Mkhize, Dennis S. Nyamori, Vincent O. Bala, Muhammad D. |
| author_facet | Mkhize, Dennis S. Nyamori, Vincent O. Bala, Muhammad D. |
| author_sort | Mkhize, Dennis S. |
| collection | PubMed |
| description | The title compound, [Fe(C(5)H(5))(C(8)H(9)S)(CO)(2)], is a three-legged piano-stool iron(II) complex that is characterized by a thioethyl-linked phenyl ring and a cyclopentadienyl moiety that occupies the apical coordination site. The two aromatic rings are essentially planar with the same maximum deviation of 0.009 Å. The mean planes of the phenyl and cyclopentadienyl rings bisect at an acute angle of 50.08°. |
| format | Text |
| id | pubmed-3089356 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30893562011-07-13 Dicarbonyl(η(5)-cyclopentadienyl)[2-(phenylsulfanyl)ethyl]iron(II) Mkhize, Dennis S. Nyamori, Vincent O. Bala, Muhammad D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(5)H(5))(C(8)H(9)S)(CO)(2)], is a three-legged piano-stool iron(II) complex that is characterized by a thioethyl-linked phenyl ring and a cyclopentadienyl moiety that occupies the apical coordination site. The two aromatic rings are essentially planar with the same maximum deviation of 0.009 Å. The mean planes of the phenyl and cyclopentadienyl rings bisect at an acute angle of 50.08°. International Union of Crystallography 2011-04-29 /pmc/articles/PMC3089356/ /pubmed/21754351 http://dx.doi.org/10.1107/S160053681101511X Text en © Mkhize et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Mkhize, Dennis S. Nyamori, Vincent O. Bala, Muhammad D. Dicarbonyl(η(5)-cyclopentadienyl)[2-(phenylsulfanyl)ethyl]iron(II) |
| title | Dicarbonyl(η(5)-cyclopentadienyl)[2-(phenylsulfanyl)ethyl]iron(II) |
| title_full | Dicarbonyl(η(5)-cyclopentadienyl)[2-(phenylsulfanyl)ethyl]iron(II) |
| title_fullStr | Dicarbonyl(η(5)-cyclopentadienyl)[2-(phenylsulfanyl)ethyl]iron(II) |
| title_full_unstemmed | Dicarbonyl(η(5)-cyclopentadienyl)[2-(phenylsulfanyl)ethyl]iron(II) |
| title_short | Dicarbonyl(η(5)-cyclopentadienyl)[2-(phenylsulfanyl)ethyl]iron(II) |
| title_sort | dicarbonyl(η(5)-cyclopentadienyl)[2-(phenylsulfanyl)ethyl]iron(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089356/ https://www.ncbi.nlm.nih.gov/pubmed/21754351 http://dx.doi.org/10.1107/S160053681101511X |
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