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(2-Hydroxyacetato-κO (1))bis(1,10-phenanthroline-κ(2) N,N′)copper(II) nitrate
In the title compound, [Cu(C(2)H(3)O(3))(C(12)H(8)N(2))(2)]NO(3), the Cu(II) atom is coordinated by two phenanthroline (phen) ligands and one carboxyl-O atom of a hydroxyacetate anion in a distorted square-pyramidal geometry. The hydroxy group of the hydroxyacetate ligand links with the counter...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089357/ https://www.ncbi.nlm.nih.gov/pubmed/21754313 http://dx.doi.org/10.1107/S1600536811013110 |
Sumario: | In the title compound, [Cu(C(2)H(3)O(3))(C(12)H(8)N(2))(2)]NO(3), the Cu(II) atom is coordinated by two phenanthroline (phen) ligands and one carboxyl-O atom of a hydroxyacetate anion in a distorted square-pyramidal geometry. The hydroxy group of the hydroxyacetate ligand links with the counter NO(3) (−) anion via a pair of bifurcated O—H⋯O hydrogen bonds. The centroid–centroid distance of 3.5676 (14) Å between benzene rings of parallel phen ligands of adjacent molecules suggests the existence of π–π stacking. Weak intermolecular C—H⋯O hydrogen bonding is also present in the crystal structure. |
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