(2-Hy­droxy­acetato-κO (1))bis­(1,10-phenan­throline-κ(2) N,N′)copper(II) nitrate

In the title compound, [Cu(C(2)H(3)O(3))(C(12)H(8)N(2))(2)]NO(3), the Cu(II) atom is coordinated by two phenanthroline (phen) ligands and one carboxyl-O atom of a hy­droxy­acetate anion in a distorted square-pyramidal geometry. The hy­droxy group of the hy­droxy­acetate ligand links with the counter...

Descripción completa

Detalles Bibliográficos
Autores principales: Kong, Ya-Jie, Yuan, Zhuang-Dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089357/
https://www.ncbi.nlm.nih.gov/pubmed/21754313
http://dx.doi.org/10.1107/S1600536811013110
_version_ 1782203038515068928
author Kong, Ya-Jie
Yuan, Zhuang-Dong
author_facet Kong, Ya-Jie
Yuan, Zhuang-Dong
author_sort Kong, Ya-Jie
collection PubMed
description In the title compound, [Cu(C(2)H(3)O(3))(C(12)H(8)N(2))(2)]NO(3), the Cu(II) atom is coordinated by two phenanthroline (phen) ligands and one carboxyl-O atom of a hy­droxy­acetate anion in a distorted square-pyramidal geometry. The hy­droxy group of the hy­droxy­acetate ligand links with the counter NO(3) (−) anion via a pair of bifurcated O—H⋯O hydrogen bonds. The centroid–centroid distance of 3.5676 (14) Å between benzene rings of parallel phen ligands of adjacent mol­ecules suggests the existence of π–π stacking. Weak inter­molecular C—H⋯O hydrogen bonding is also present in the crystal structure.
format Text
id pubmed-3089357
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30893572011-07-13 (2-Hy­droxy­acetato-κO (1))bis­(1,10-phenan­throline-κ(2) N,N′)copper(II) nitrate Kong, Ya-Jie Yuan, Zhuang-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(2)H(3)O(3))(C(12)H(8)N(2))(2)]NO(3), the Cu(II) atom is coordinated by two phenanthroline (phen) ligands and one carboxyl-O atom of a hy­droxy­acetate anion in a distorted square-pyramidal geometry. The hy­droxy group of the hy­droxy­acetate ligand links with the counter NO(3) (−) anion via a pair of bifurcated O—H⋯O hydrogen bonds. The centroid–centroid distance of 3.5676 (14) Å between benzene rings of parallel phen ligands of adjacent mol­ecules suggests the existence of π–π stacking. Weak inter­molecular C—H⋯O hydrogen bonding is also present in the crystal structure. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089357/ /pubmed/21754313 http://dx.doi.org/10.1107/S1600536811013110 Text en © Kong and Yuan 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kong, Ya-Jie
Yuan, Zhuang-Dong
(2-Hy­droxy­acetato-κO (1))bis­(1,10-phenan­throline-κ(2) N,N′)copper(II) nitrate
title (2-Hy­droxy­acetato-κO (1))bis­(1,10-phenan­throline-κ(2) N,N′)copper(II) nitrate
title_full (2-Hy­droxy­acetato-κO (1))bis­(1,10-phenan­throline-κ(2) N,N′)copper(II) nitrate
title_fullStr (2-Hy­droxy­acetato-κO (1))bis­(1,10-phenan­throline-κ(2) N,N′)copper(II) nitrate
title_full_unstemmed (2-Hy­droxy­acetato-κO (1))bis­(1,10-phenan­throline-κ(2) N,N′)copper(II) nitrate
title_short (2-Hy­droxy­acetato-κO (1))bis­(1,10-phenan­throline-κ(2) N,N′)copper(II) nitrate
title_sort (2-hy­droxy­acetato-κo (1))bis­(1,10-phenan­throline-κ(2) n,n′)copper(ii) nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089357/
https://www.ncbi.nlm.nih.gov/pubmed/21754313
http://dx.doi.org/10.1107/S1600536811013110
work_keys_str_mv AT kongyajie 2hydroxyacetatoko1bis110phenanthrolinek2nncopperiinitrate
AT yuanzhuangdong 2hydroxyacetatoko1bis110phenanthrolinek2nncopperiinitrate

Ejemplares similares