rac-5-Acetyl-6-hy­droxy-3,6-dimethyl-4-phenyl-4,5,6,7-tetra­hydro-2H-indazole

The title compound, C(17)H(20)N(2)O(2), is chiral but crystallizes in a centrosymmetric space group as a racemate, the relative configuration at the stereogenic centres being 2S*,3R*,4S*. The cyclo­hexane ring adopts a half-chair conformation while the pyrazole ring has an envelope conformation. The...

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Autores principales: Maharramov, Abel M., Ismiyev, Arif I., Rashidov, Bahruz A., Aliyev, Ilkin V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089358/
https://www.ncbi.nlm.nih.gov/pubmed/21754439
http://dx.doi.org/10.1107/S1600536811013195
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author Maharramov, Abel M.
Ismiyev, Arif I.
Rashidov, Bahruz A.
Aliyev, Ilkin V.
author_facet Maharramov, Abel M.
Ismiyev, Arif I.
Rashidov, Bahruz A.
Aliyev, Ilkin V.
author_sort Maharramov, Abel M.
collection PubMed
description The title compound, C(17)H(20)N(2)O(2), is chiral but crystallizes in a centrosymmetric space group as a racemate, the relative configuration at the stereogenic centres being 2S*,3R*,4S*. The cyclo­hexane ring adopts a half-chair conformation while the pyrazole ring has an envelope conformation. The crystal packing displays inter­molecular O—H⋯N and N—H⋯O hydrogen bonding.
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spelling pubmed-30893582011-07-13 rac-5-Acetyl-6-hy­droxy-3,6-dimethyl-4-phenyl-4,5,6,7-tetra­hydro-2H-indazole Maharramov, Abel M. Ismiyev, Arif I. Rashidov, Bahruz A. Aliyev, Ilkin V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(20)N(2)O(2), is chiral but crystallizes in a centrosymmetric space group as a racemate, the relative configuration at the stereogenic centres being 2S*,3R*,4S*. The cyclo­hexane ring adopts a half-chair conformation while the pyrazole ring has an envelope conformation. The crystal packing displays inter­molecular O—H⋯N and N—H⋯O hydrogen bonding. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089358/ /pubmed/21754439 http://dx.doi.org/10.1107/S1600536811013195 Text en © Maharramov et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Maharramov, Abel M.
Ismiyev, Arif I.
Rashidov, Bahruz A.
Aliyev, Ilkin V.
rac-5-Acetyl-6-hy­droxy-3,6-dimethyl-4-phenyl-4,5,6,7-tetra­hydro-2H-indazole
title rac-5-Acetyl-6-hy­droxy-3,6-dimethyl-4-phenyl-4,5,6,7-tetra­hydro-2H-indazole
title_full rac-5-Acetyl-6-hy­droxy-3,6-dimethyl-4-phenyl-4,5,6,7-tetra­hydro-2H-indazole
title_fullStr rac-5-Acetyl-6-hy­droxy-3,6-dimethyl-4-phenyl-4,5,6,7-tetra­hydro-2H-indazole
title_full_unstemmed rac-5-Acetyl-6-hy­droxy-3,6-dimethyl-4-phenyl-4,5,6,7-tetra­hydro-2H-indazole
title_short rac-5-Acetyl-6-hy­droxy-3,6-dimethyl-4-phenyl-4,5,6,7-tetra­hydro-2H-indazole
title_sort rac-5-acetyl-6-hy­droxy-3,6-dimethyl-4-phenyl-4,5,6,7-tetra­hydro-2h-indazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089358/
https://www.ncbi.nlm.nih.gov/pubmed/21754439
http://dx.doi.org/10.1107/S1600536811013195
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AT rashidovbahruza rac5acetyl6hydroxy36dimethyl4phenyl4567tetrahydro2hindazole
AT aliyevilkinv rac5acetyl6hydroxy36dimethyl4phenyl4567tetrahydro2hindazole

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