Cargando…

(2,2′-Bipyridine-κ(2) N,N′)bis­(N-isopropyl-N-methyl­dithio­carbamato-κ(2) S,S′)cadmium

The Cd(II) atom in the title compound, [Cd(C(5)H(10)NS(2))(2)(C(10)H(8)N(2))], exists in an N(2)S(4) donor set defined by two chelating dithio­carbamate anions as well as a 2,2′-bipyridine ligand. The coordination geometry approximates a trigonal prism. The crystal packing features weak C—H⋯S inter­...

Descripción completa

Detalles Bibliográficos
Autores principales: Wahab, Nor Asiken Abdul, Baba, Ibrahim, Mohamed Tahir, Mohamed Ibrahim, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089361/
https://www.ncbi.nlm.nih.gov/pubmed/21754287
http://dx.doi.org/10.1107/S1600536811012414
Descripción
Sumario:The Cd(II) atom in the title compound, [Cd(C(5)H(10)NS(2))(2)(C(10)H(8)N(2))], exists in an N(2)S(4) donor set defined by two chelating dithio­carbamate anions as well as a 2,2′-bipyridine ligand. The coordination geometry approximates a trigonal prism. The crystal packing features weak C—H⋯S inter­actions, leading to linear supra­molecular chains along the a axis. The primary connections between these are by π–π stacking inter­actions [ring centroid distance between centrosymmetrically related pyridyl rings = 3.7455 (10) Å]. Overall, the crystal structure may be described as comprising double layers of mol­ecules that stack along the b axis.