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(2,2′-Bipyridine-κ(2) N,N′)bis­(N-isopropyl-N-methyl­dithio­carbamato-κ(2) S,S′)cadmium

The Cd(II) atom in the title compound, [Cd(C(5)H(10)NS(2))(2)(C(10)H(8)N(2))], exists in an N(2)S(4) donor set defined by two chelating dithio­carbamate anions as well as a 2,2′-bipyridine ligand. The coordination geometry approximates a trigonal prism. The crystal packing features weak C—H⋯S inter­...

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Detalles Bibliográficos
Autores principales: Wahab, Nor Asiken Abdul, Baba, Ibrahim, Mohamed Tahir, Mohamed Ibrahim, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089361/
https://www.ncbi.nlm.nih.gov/pubmed/21754287
http://dx.doi.org/10.1107/S1600536811012414
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author Wahab, Nor Asiken Abdul
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
author_facet Wahab, Nor Asiken Abdul
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
author_sort Wahab, Nor Asiken Abdul
collection PubMed
description The Cd(II) atom in the title compound, [Cd(C(5)H(10)NS(2))(2)(C(10)H(8)N(2))], exists in an N(2)S(4) donor set defined by two chelating dithio­carbamate anions as well as a 2,2′-bipyridine ligand. The coordination geometry approximates a trigonal prism. The crystal packing features weak C—H⋯S inter­actions, leading to linear supra­molecular chains along the a axis. The primary connections between these are by π–π stacking inter­actions [ring centroid distance between centrosymmetrically related pyridyl rings = 3.7455 (10) Å]. Overall, the crystal structure may be described as comprising double layers of mol­ecules that stack along the b axis.
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spelling pubmed-30893612011-07-13 (2,2′-Bipyridine-κ(2) N,N′)bis­(N-isopropyl-N-methyl­dithio­carbamato-κ(2) S,S′)cadmium Wahab, Nor Asiken Abdul Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cd(II) atom in the title compound, [Cd(C(5)H(10)NS(2))(2)(C(10)H(8)N(2))], exists in an N(2)S(4) donor set defined by two chelating dithio­carbamate anions as well as a 2,2′-bipyridine ligand. The coordination geometry approximates a trigonal prism. The crystal packing features weak C—H⋯S inter­actions, leading to linear supra­molecular chains along the a axis. The primary connections between these are by π–π stacking inter­actions [ring centroid distance between centrosymmetrically related pyridyl rings = 3.7455 (10) Å]. Overall, the crystal structure may be described as comprising double layers of mol­ecules that stack along the b axis. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089361/ /pubmed/21754287 http://dx.doi.org/10.1107/S1600536811012414 Text en © Wahab et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wahab, Nor Asiken Abdul
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
(2,2′-Bipyridine-κ(2) N,N′)bis­(N-isopropyl-N-methyl­dithio­carbamato-κ(2) S,S′)cadmium
title (2,2′-Bipyridine-κ(2) N,N′)bis­(N-isopropyl-N-methyl­dithio­carbamato-κ(2) S,S′)cadmium
title_full (2,2′-Bipyridine-κ(2) N,N′)bis­(N-isopropyl-N-methyl­dithio­carbamato-κ(2) S,S′)cadmium
title_fullStr (2,2′-Bipyridine-κ(2) N,N′)bis­(N-isopropyl-N-methyl­dithio­carbamato-κ(2) S,S′)cadmium
title_full_unstemmed (2,2′-Bipyridine-κ(2) N,N′)bis­(N-isopropyl-N-methyl­dithio­carbamato-κ(2) S,S′)cadmium
title_short (2,2′-Bipyridine-κ(2) N,N′)bis­(N-isopropyl-N-methyl­dithio­carbamato-κ(2) S,S′)cadmium
title_sort (2,2′-bipyridine-κ(2) n,n′)bis­(n-isopropyl-n-methyl­dithio­carbamato-κ(2) s,s′)cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089361/
https://www.ncbi.nlm.nih.gov/pubmed/21754287
http://dx.doi.org/10.1107/S1600536811012414
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