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(2,2′-Bipyridine-κ(2) N,N′)bis(N-isopropyl-N-methyldithiocarbamato-κ(2) S,S′)cadmium
The Cd(II) atom in the title compound, [Cd(C(5)H(10)NS(2))(2)(C(10)H(8)N(2))], exists in an N(2)S(4) donor set defined by two chelating dithiocarbamate anions as well as a 2,2′-bipyridine ligand. The coordination geometry approximates a trigonal prism. The crystal packing features weak C—H⋯S inter...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089361/ https://www.ncbi.nlm.nih.gov/pubmed/21754287 http://dx.doi.org/10.1107/S1600536811012414 |
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author | Wahab, Nor Asiken Abdul Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
author_facet | Wahab, Nor Asiken Abdul Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
author_sort | Wahab, Nor Asiken Abdul |
collection | PubMed |
description | The Cd(II) atom in the title compound, [Cd(C(5)H(10)NS(2))(2)(C(10)H(8)N(2))], exists in an N(2)S(4) donor set defined by two chelating dithiocarbamate anions as well as a 2,2′-bipyridine ligand. The coordination geometry approximates a trigonal prism. The crystal packing features weak C—H⋯S interactions, leading to linear supramolecular chains along the a axis. The primary connections between these are by π–π stacking interactions [ring centroid distance between centrosymmetrically related pyridyl rings = 3.7455 (10) Å]. Overall, the crystal structure may be described as comprising double layers of molecules that stack along the b axis. |
format | Text |
id | pubmed-3089361 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30893612011-07-13 (2,2′-Bipyridine-κ(2) N,N′)bis(N-isopropyl-N-methyldithiocarbamato-κ(2) S,S′)cadmium Wahab, Nor Asiken Abdul Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cd(II) atom in the title compound, [Cd(C(5)H(10)NS(2))(2)(C(10)H(8)N(2))], exists in an N(2)S(4) donor set defined by two chelating dithiocarbamate anions as well as a 2,2′-bipyridine ligand. The coordination geometry approximates a trigonal prism. The crystal packing features weak C—H⋯S interactions, leading to linear supramolecular chains along the a axis. The primary connections between these are by π–π stacking interactions [ring centroid distance between centrosymmetrically related pyridyl rings = 3.7455 (10) Å]. Overall, the crystal structure may be described as comprising double layers of molecules that stack along the b axis. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089361/ /pubmed/21754287 http://dx.doi.org/10.1107/S1600536811012414 Text en © Wahab et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wahab, Nor Asiken Abdul Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. (2,2′-Bipyridine-κ(2) N,N′)bis(N-isopropyl-N-methyldithiocarbamato-κ(2) S,S′)cadmium |
title | (2,2′-Bipyridine-κ(2)
N,N′)bis(N-isopropyl-N-methyldithiocarbamato-κ(2)
S,S′)cadmium |
title_full | (2,2′-Bipyridine-κ(2)
N,N′)bis(N-isopropyl-N-methyldithiocarbamato-κ(2)
S,S′)cadmium |
title_fullStr | (2,2′-Bipyridine-κ(2)
N,N′)bis(N-isopropyl-N-methyldithiocarbamato-κ(2)
S,S′)cadmium |
title_full_unstemmed | (2,2′-Bipyridine-κ(2)
N,N′)bis(N-isopropyl-N-methyldithiocarbamato-κ(2)
S,S′)cadmium |
title_short | (2,2′-Bipyridine-κ(2)
N,N′)bis(N-isopropyl-N-methyldithiocarbamato-κ(2)
S,S′)cadmium |
title_sort | (2,2′-bipyridine-κ(2)
n,n′)bis(n-isopropyl-n-methyldithiocarbamato-κ(2)
s,s′)cadmium |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089361/ https://www.ncbi.nlm.nih.gov/pubmed/21754287 http://dx.doi.org/10.1107/S1600536811012414 |
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