Cargando…

Bis(μ-hexa­deca­noato-κ(2) O:O)bis­[(2,2′-bipyridine-κ(2) N,N′)(hexa­deca­noato-κO)copper(II)] methanol disolvate

The asymmetric unit of the title compound, [Cu(2)(C(16)H(31)O(2))(4)(C(10)H(8)N(2))(2)]·2CH(3)OH, contains one half-mol­ecule of the metal complex solvated by a methanol mol­ecule. In the complex, two of the metal atoms are doubly bridged by two monodentate bridging hexa­deca­noate ligands around a...

Descripción completa

Detalles Bibliográficos
Autores principales: Che Mat, Ahmad Nazeer, Abdullah, Norbani, Khaledi, Hamid, Tee, Jia Ti
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089362/
https://www.ncbi.nlm.nih.gov/pubmed/21754319
http://dx.doi.org/10.1107/S1600536811013559
_version_ 1782203039706251264
author Che Mat, Ahmad Nazeer
Abdullah, Norbani
Khaledi, Hamid
Tee, Jia Ti
author_facet Che Mat, Ahmad Nazeer
Abdullah, Norbani
Khaledi, Hamid
Tee, Jia Ti
author_sort Che Mat, Ahmad Nazeer
collection PubMed
description The asymmetric unit of the title compound, [Cu(2)(C(16)H(31)O(2))(4)(C(10)H(8)N(2))(2)]·2CH(3)OH, contains one half-mol­ecule of the metal complex solvated by a methanol mol­ecule. In the complex, two of the metal atoms are doubly bridged by two monodentate bridging hexa­deca­noate ligands around a center of inversion. The square-pyramidal geometry around each Cu(II) ion is completed by a terminal hexa­deca­noate O atom and two N atoms from a 2,2′-bipyridine ligand. The alkyl chains of the carboxyl­ate ligands are arranged in a parallel manner with an all-trans conformation. In the crystal, a π–π inter­action formed by the bipyridine rings [centroid–centroid separation = 3.7723 (17) Å] and inter­molecular C—H⋯O hydrogen bonds link the complex mol­ecules into infinite chains along the b axis. An O—H⋯O interaction between the methanol solvate and one of the carboxylate O atoms is also observed.
format Text
id pubmed-3089362
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30893622011-07-13 Bis(μ-hexa­deca­noato-κ(2) O:O)bis­[(2,2′-bipyridine-κ(2) N,N′)(hexa­deca­noato-κO)copper(II)] methanol disolvate Che Mat, Ahmad Nazeer Abdullah, Norbani Khaledi, Hamid Tee, Jia Ti Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(2)(C(16)H(31)O(2))(4)(C(10)H(8)N(2))(2)]·2CH(3)OH, contains one half-mol­ecule of the metal complex solvated by a methanol mol­ecule. In the complex, two of the metal atoms are doubly bridged by two monodentate bridging hexa­deca­noate ligands around a center of inversion. The square-pyramidal geometry around each Cu(II) ion is completed by a terminal hexa­deca­noate O atom and two N atoms from a 2,2′-bipyridine ligand. The alkyl chains of the carboxyl­ate ligands are arranged in a parallel manner with an all-trans conformation. In the crystal, a π–π inter­action formed by the bipyridine rings [centroid–centroid separation = 3.7723 (17) Å] and inter­molecular C—H⋯O hydrogen bonds link the complex mol­ecules into infinite chains along the b axis. An O—H⋯O interaction between the methanol solvate and one of the carboxylate O atoms is also observed. International Union of Crystallography 2011-04-16 /pmc/articles/PMC3089362/ /pubmed/21754319 http://dx.doi.org/10.1107/S1600536811013559 Text en © Che Mat et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Che Mat, Ahmad Nazeer
Abdullah, Norbani
Khaledi, Hamid
Tee, Jia Ti
Bis(μ-hexa­deca­noato-κ(2) O:O)bis­[(2,2′-bipyridine-κ(2) N,N′)(hexa­deca­noato-κO)copper(II)] methanol disolvate
title Bis(μ-hexa­deca­noato-κ(2) O:O)bis­[(2,2′-bipyridine-κ(2) N,N′)(hexa­deca­noato-κO)copper(II)] methanol disolvate
title_full Bis(μ-hexa­deca­noato-κ(2) O:O)bis­[(2,2′-bipyridine-κ(2) N,N′)(hexa­deca­noato-κO)copper(II)] methanol disolvate
title_fullStr Bis(μ-hexa­deca­noato-κ(2) O:O)bis­[(2,2′-bipyridine-κ(2) N,N′)(hexa­deca­noato-κO)copper(II)] methanol disolvate
title_full_unstemmed Bis(μ-hexa­deca­noato-κ(2) O:O)bis­[(2,2′-bipyridine-κ(2) N,N′)(hexa­deca­noato-κO)copper(II)] methanol disolvate
title_short Bis(μ-hexa­deca­noato-κ(2) O:O)bis­[(2,2′-bipyridine-κ(2) N,N′)(hexa­deca­noato-κO)copper(II)] methanol disolvate
title_sort bis(μ-hexa­deca­noato-κ(2) o:o)bis­[(2,2′-bipyridine-κ(2) n,n′)(hexa­deca­noato-κo)copper(ii)] methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089362/
https://www.ncbi.nlm.nih.gov/pubmed/21754319
http://dx.doi.org/10.1107/S1600536811013559
work_keys_str_mv AT chematahmadnazeer bismhexadecanoatok2oobis22bipyridinek2nnhexadecanoatokocopperiimethanoldisolvate
AT abdullahnorbani bismhexadecanoatok2oobis22bipyridinek2nnhexadecanoatokocopperiimethanoldisolvate
AT khaledihamid bismhexadecanoatok2oobis22bipyridinek2nnhexadecanoatokocopperiimethanoldisolvate
AT teejiati bismhexadecanoatok2oobis22bipyridinek2nnhexadecanoatokocopperiimethanoldisolvate