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Bis(μ-hexadecanoato-κ(2) O:O)bis[(2,2′-bipyridine-κ(2) N,N′)(hexadecanoato-κO)copper(II)] methanol disolvate
The asymmetric unit of the title compound, [Cu(2)(C(16)H(31)O(2))(4)(C(10)H(8)N(2))(2)]·2CH(3)OH, contains one half-molecule of the metal complex solvated by a methanol molecule. In the complex, two of the metal atoms are doubly bridged by two monodentate bridging hexadecanoate ligands around a...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089362/ https://www.ncbi.nlm.nih.gov/pubmed/21754319 http://dx.doi.org/10.1107/S1600536811013559 |
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author | Che Mat, Ahmad Nazeer Abdullah, Norbani Khaledi, Hamid Tee, Jia Ti |
author_facet | Che Mat, Ahmad Nazeer Abdullah, Norbani Khaledi, Hamid Tee, Jia Ti |
author_sort | Che Mat, Ahmad Nazeer |
collection | PubMed |
description | The asymmetric unit of the title compound, [Cu(2)(C(16)H(31)O(2))(4)(C(10)H(8)N(2))(2)]·2CH(3)OH, contains one half-molecule of the metal complex solvated by a methanol molecule. In the complex, two of the metal atoms are doubly bridged by two monodentate bridging hexadecanoate ligands around a center of inversion. The square-pyramidal geometry around each Cu(II) ion is completed by a terminal hexadecanoate O atom and two N atoms from a 2,2′-bipyridine ligand. The alkyl chains of the carboxylate ligands are arranged in a parallel manner with an all-trans conformation. In the crystal, a π–π interaction formed by the bipyridine rings [centroid–centroid separation = 3.7723 (17) Å] and intermolecular C—H⋯O hydrogen bonds link the complex molecules into infinite chains along the b axis. An O—H⋯O interaction between the methanol solvate and one of the carboxylate O atoms is also observed. |
format | Text |
id | pubmed-3089362 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30893622011-07-13 Bis(μ-hexadecanoato-κ(2) O:O)bis[(2,2′-bipyridine-κ(2) N,N′)(hexadecanoato-κO)copper(II)] methanol disolvate Che Mat, Ahmad Nazeer Abdullah, Norbani Khaledi, Hamid Tee, Jia Ti Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(2)(C(16)H(31)O(2))(4)(C(10)H(8)N(2))(2)]·2CH(3)OH, contains one half-molecule of the metal complex solvated by a methanol molecule. In the complex, two of the metal atoms are doubly bridged by two monodentate bridging hexadecanoate ligands around a center of inversion. The square-pyramidal geometry around each Cu(II) ion is completed by a terminal hexadecanoate O atom and two N atoms from a 2,2′-bipyridine ligand. The alkyl chains of the carboxylate ligands are arranged in a parallel manner with an all-trans conformation. In the crystal, a π–π interaction formed by the bipyridine rings [centroid–centroid separation = 3.7723 (17) Å] and intermolecular C—H⋯O hydrogen bonds link the complex molecules into infinite chains along the b axis. An O—H⋯O interaction between the methanol solvate and one of the carboxylate O atoms is also observed. International Union of Crystallography 2011-04-16 /pmc/articles/PMC3089362/ /pubmed/21754319 http://dx.doi.org/10.1107/S1600536811013559 Text en © Che Mat et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Che Mat, Ahmad Nazeer Abdullah, Norbani Khaledi, Hamid Tee, Jia Ti Bis(μ-hexadecanoato-κ(2) O:O)bis[(2,2′-bipyridine-κ(2) N,N′)(hexadecanoato-κO)copper(II)] methanol disolvate |
title | Bis(μ-hexadecanoato-κ(2)
O:O)bis[(2,2′-bipyridine-κ(2)
N,N′)(hexadecanoato-κO)copper(II)] methanol disolvate |
title_full | Bis(μ-hexadecanoato-κ(2)
O:O)bis[(2,2′-bipyridine-κ(2)
N,N′)(hexadecanoato-κO)copper(II)] methanol disolvate |
title_fullStr | Bis(μ-hexadecanoato-κ(2)
O:O)bis[(2,2′-bipyridine-κ(2)
N,N′)(hexadecanoato-κO)copper(II)] methanol disolvate |
title_full_unstemmed | Bis(μ-hexadecanoato-κ(2)
O:O)bis[(2,2′-bipyridine-κ(2)
N,N′)(hexadecanoato-κO)copper(II)] methanol disolvate |
title_short | Bis(μ-hexadecanoato-κ(2)
O:O)bis[(2,2′-bipyridine-κ(2)
N,N′)(hexadecanoato-κO)copper(II)] methanol disolvate |
title_sort | bis(μ-hexadecanoato-κ(2)
o:o)bis[(2,2′-bipyridine-κ(2)
n,n′)(hexadecanoato-κo)copper(ii)] methanol disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089362/ https://www.ncbi.nlm.nih.gov/pubmed/21754319 http://dx.doi.org/10.1107/S1600536811013559 |
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