trans-Dichloridobis[(pyridin-4-yl)boronic acid-κN]palladium(II) dimethyl sulfoxide disolvate

In the title compound, [PdCl(2)(C(5)H(6)BNO(2))(2)]·2C(2)H(6)OS, the Pd(II) ion is located on an inversion centre and is four-coordinated in a trans square-planar geometry by two chloride ions and two (pyridin-4-yl)boronic acid ligands. The Pd—N and Pd—Cl distances are 2.023 (2) and 2.2977 (7) Å, re...

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Detalles Bibliográficos
Autores principales: Duong, Adam, Wuest, James D., Maris, Thierry
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089363/
https://www.ncbi.nlm.nih.gov/pubmed/21754261
http://dx.doi.org/10.1107/S1600536811010713
Descripción
Sumario:In the title compound, [PdCl(2)(C(5)H(6)BNO(2))(2)]·2C(2)H(6)OS, the Pd(II) ion is located on an inversion centre and is four-coordinated in a trans square-planar geometry by two chloride ions and two (pyridin-4-yl)boronic acid ligands. The Pd—N and Pd—Cl distances are 2.023 (2) and 2.2977 (7) Å, respectively, and the average N—Pd—Cl angle is 90°. The dimethyl sulfoxide solvent mol­ecules play a key role in the crystal structure by bridging the complex mol­ecules via O—H⋯O hydrogen bonds, forming tapes running along the b axis. C—H⋯O inter­actions also contribute to the cohesion of the crystal.

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