trans-Dichloridobis[(pyridin-4-yl)boronic acid-κN]palladium(II) dimethyl sulfoxide disolvate

In the title compound, [PdCl(2)(C(5)H(6)BNO(2))(2)]·2C(2)H(6)OS, the Pd(II) ion is located on an inversion centre and is four-coordinated in a trans square-planar geometry by two chloride ions and two (pyridin-4-yl)boronic acid ligands. The Pd—N and Pd—Cl distances are 2.023 (2) and 2.2977 (7) Å, re...

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Detalles Bibliográficos
Autores principales: Duong, Adam, Wuest, James D., Maris, Thierry
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089363/
https://www.ncbi.nlm.nih.gov/pubmed/21754261
http://dx.doi.org/10.1107/S1600536811010713
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author Duong, Adam
Wuest, James D.
Maris, Thierry
author_facet Duong, Adam
Wuest, James D.
Maris, Thierry
author_sort Duong, Adam
collection PubMed
description In the title compound, [PdCl(2)(C(5)H(6)BNO(2))(2)]·2C(2)H(6)OS, the Pd(II) ion is located on an inversion centre and is four-coordinated in a trans square-planar geometry by two chloride ions and two (pyridin-4-yl)boronic acid ligands. The Pd—N and Pd—Cl distances are 2.023 (2) and 2.2977 (7) Å, respectively, and the average N—Pd—Cl angle is 90°. The dimethyl sulfoxide solvent mol­ecules play a key role in the crystal structure by bridging the complex mol­ecules via O—H⋯O hydrogen bonds, forming tapes running along the b axis. C—H⋯O inter­actions also contribute to the cohesion of the crystal.
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spelling pubmed-30893632011-07-13 trans-Dichloridobis[(pyridin-4-yl)boronic acid-κN]palladium(II) dimethyl sulfoxide disolvate Duong, Adam Wuest, James D. Maris, Thierry Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdCl(2)(C(5)H(6)BNO(2))(2)]·2C(2)H(6)OS, the Pd(II) ion is located on an inversion centre and is four-coordinated in a trans square-planar geometry by two chloride ions and two (pyridin-4-yl)boronic acid ligands. The Pd—N and Pd—Cl distances are 2.023 (2) and 2.2977 (7) Å, respectively, and the average N—Pd—Cl angle is 90°. The dimethyl sulfoxide solvent mol­ecules play a key role in the crystal structure by bridging the complex mol­ecules via O—H⋯O hydrogen bonds, forming tapes running along the b axis. C—H⋯O inter­actions also contribute to the cohesion of the crystal. International Union of Crystallography 2011-04-07 /pmc/articles/PMC3089363/ /pubmed/21754261 http://dx.doi.org/10.1107/S1600536811010713 Text en © Duong et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Duong, Adam
Wuest, James D.
Maris, Thierry
trans-Dichloridobis[(pyridin-4-yl)boronic acid-κN]palladium(II) dimethyl sulfoxide disolvate
title trans-Dichloridobis[(pyridin-4-yl)boronic acid-κN]palladium(II) dimethyl sulfoxide disolvate
title_full trans-Dichloridobis[(pyridin-4-yl)boronic acid-κN]palladium(II) dimethyl sulfoxide disolvate
title_fullStr trans-Dichloridobis[(pyridin-4-yl)boronic acid-κN]palladium(II) dimethyl sulfoxide disolvate
title_full_unstemmed trans-Dichloridobis[(pyridin-4-yl)boronic acid-κN]palladium(II) dimethyl sulfoxide disolvate
title_short trans-Dichloridobis[(pyridin-4-yl)boronic acid-κN]palladium(II) dimethyl sulfoxide disolvate
title_sort trans-dichloridobis[(pyridin-4-yl)boronic acid-κn]palladium(ii) dimethyl sulfoxide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089363/
https://www.ncbi.nlm.nih.gov/pubmed/21754261
http://dx.doi.org/10.1107/S1600536811010713
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AT maristhierry transdichloridobispyridin4ylboronicacidknpalladiumiidimethylsulfoxidedisolvate

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