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Diaqua(2,2′-bipyridine-κ(2) N,N′)bis(perchlorato-κO)copper(II)
The central CuN(2)O(4) motif of the title compound, [Cu(ClO(4))(2)(C(10)H(8)N(2))(H(2)O)(2)], exhibits a Jahn–Teller-distorted octahedral geometry around the metal atom, showing a considerably long Cu—O bond distance of 2.5058 (12) Å towards the second perchlorate group, giving a (4 + 1+1)-type coo...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089365/ https://www.ncbi.nlm.nih.gov/pubmed/21754328 http://dx.doi.org/10.1107/S1600536811013808 |
| Sumario: | The central CuN(2)O(4) motif of the title compound, [Cu(ClO(4))(2)(C(10)H(8)N(2))(H(2)O)(2)], exhibits a Jahn–Teller-distorted octahedral geometry around the metal atom, showing a considerably long Cu—O bond distance of 2.5058 (12) Å towards the second perchlorate group, giving a (4 + 1+1)-type coordination mode. In the crystal, the components are linked via intermolecular O—H⋯O hydrogen bonds, forming layers parallel to (001). Additional stabilization within these layers is provided by π–π [centroid–centroid distances of 3.7848 (9)–4.4231 (9) Å] stacking interactions. |
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