Diaqua­(2,2′-bipyridine-κ(2) N,N′)bis­(perchlorato-κO)copper(II)

The central CuN(2)O(4) motif of the title compound, [Cu(ClO(4))(2)(C(10)H(8)N(2))(H(2)O)(2)], exhibits a Jahn–Teller-distorted octa­hedral geometry around the metal atom, showing a considerably long Cu—O bond distance of 2.5058 (12) Å towards the second perchlorate group, giving a (4 + 1+1)-type coo...

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Autores principales: Damous, Maamar, Hamlaoui, Meriem, Bouacida, Sofiane, Merazig, Hocine, Daran, Jean-Claude
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089365/
https://www.ncbi.nlm.nih.gov/pubmed/21754328
http://dx.doi.org/10.1107/S1600536811013808
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author Damous, Maamar
Hamlaoui, Meriem
Bouacida, Sofiane
Merazig, Hocine
Daran, Jean-Claude
author_facet Damous, Maamar
Hamlaoui, Meriem
Bouacida, Sofiane
Merazig, Hocine
Daran, Jean-Claude
author_sort Damous, Maamar
collection PubMed
description The central CuN(2)O(4) motif of the title compound, [Cu(ClO(4))(2)(C(10)H(8)N(2))(H(2)O)(2)], exhibits a Jahn–Teller-distorted octa­hedral geometry around the metal atom, showing a considerably long Cu—O bond distance of 2.5058 (12) Å towards the second perchlorate group, giving a (4 + 1+1)-type coordination mode. In the crystal, the components are linked via inter­molecular O—H⋯O hydrogen bonds, forming layers parallel to (001). Additional stabilization within these layers is provided by π–π [centroid–centroid distances of 3.7848 (9)–4.4231 (9) Å] stacking inter­actions.
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spelling pubmed-30893652011-07-13 Diaqua­(2,2′-bipyridine-κ(2) N,N′)bis­(perchlorato-κO)copper(II) Damous, Maamar Hamlaoui, Meriem Bouacida, Sofiane Merazig, Hocine Daran, Jean-Claude Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The central CuN(2)O(4) motif of the title compound, [Cu(ClO(4))(2)(C(10)H(8)N(2))(H(2)O)(2)], exhibits a Jahn–Teller-distorted octa­hedral geometry around the metal atom, showing a considerably long Cu—O bond distance of 2.5058 (12) Å towards the second perchlorate group, giving a (4 + 1+1)-type coordination mode. In the crystal, the components are linked via inter­molecular O—H⋯O hydrogen bonds, forming layers parallel to (001). Additional stabilization within these layers is provided by π–π [centroid–centroid distances of 3.7848 (9)–4.4231 (9) Å] stacking inter­actions. International Union of Crystallography 2011-04-16 /pmc/articles/PMC3089365/ /pubmed/21754328 http://dx.doi.org/10.1107/S1600536811013808 Text en © Damous et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Damous, Maamar
Hamlaoui, Meriem
Bouacida, Sofiane
Merazig, Hocine
Daran, Jean-Claude
Diaqua­(2,2′-bipyridine-κ(2) N,N′)bis­(perchlorato-κO)copper(II)
title Diaqua­(2,2′-bipyridine-κ(2) N,N′)bis­(perchlorato-κO)copper(II)
title_full Diaqua­(2,2′-bipyridine-κ(2) N,N′)bis­(perchlorato-κO)copper(II)
title_fullStr Diaqua­(2,2′-bipyridine-κ(2) N,N′)bis­(perchlorato-κO)copper(II)
title_full_unstemmed Diaqua­(2,2′-bipyridine-κ(2) N,N′)bis­(perchlorato-κO)copper(II)
title_short Diaqua­(2,2′-bipyridine-κ(2) N,N′)bis­(perchlorato-κO)copper(II)
title_sort diaqua­(2,2′-bipyridine-κ(2) n,n′)bis­(perchlorato-κo)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089365/
https://www.ncbi.nlm.nih.gov/pubmed/21754328
http://dx.doi.org/10.1107/S1600536811013808
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AT bouacidasofiane diaqua22bipyridinek2nnbisperchloratokocopperii
AT merazighocine diaqua22bipyridinek2nnbisperchloratokocopperii
AT daranjeanclaude diaqua22bipyridinek2nnbisperchloratokocopperii

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