(3R,4S)-3,4-Isopropyl­idenedioxy-3,4-dihydro-2H-pyrrole 1-oxide

The title compound C(7)H(11)NO(3) was prepared by intra­molecular nucleophilic displacement of 2,3-O-iso-propyl­idene-d-erythronolactol. There are two mol­ecules in the asymmetric unit, which are related by a pseudo-inversion centre. The crystal structure determination confirms unequivocally the con...

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Detalles Bibliográficos
Autores principales: Flores, Mari Fe, Garcia, Pilar, M. Garrido, Narciso, Sanz, Francisca, Diez, David
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089370/
https://www.ncbi.nlm.nih.gov/pubmed/21754432
http://dx.doi.org/10.1107/S1600536811013055
Descripción
Sumario:The title compound C(7)H(11)NO(3) was prepared by intra­molecular nucleophilic displacement of 2,3-O-iso-propyl­idene-d-erythronolactol. There are two mol­ecules in the asymmetric unit, which are related by a pseudo-inversion centre. The crystal structure determination confirms unequivocally the configuration of the chiral centres as 3S,4R. In the crystal structure, inter­molecular C—H⋯O inter­actions link the mol­ecules (into infinite zigzag chains along the a axis.

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