(3R,4S)-3,4-Isopropyl­idenedioxy-3,4-dihydro-2H-pyrrole 1-oxide

The title compound C(7)H(11)NO(3) was prepared by intra­molecular nucleophilic displacement of 2,3-O-iso-propyl­idene-d-erythronolactol. There are two mol­ecules in the asymmetric unit, which are related by a pseudo-inversion centre. The crystal structure determination confirms unequivocally the con...

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Detalles Bibliográficos
Autores principales: Flores, Mari Fe, Garcia, Pilar, M. Garrido, Narciso, Sanz, Francisca, Diez, David
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089370/
https://www.ncbi.nlm.nih.gov/pubmed/21754432
http://dx.doi.org/10.1107/S1600536811013055
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author Flores, Mari Fe
Garcia, Pilar
M. Garrido, Narciso
Sanz, Francisca
Diez, David
author_facet Flores, Mari Fe
Garcia, Pilar
M. Garrido, Narciso
Sanz, Francisca
Diez, David
author_sort Flores, Mari Fe
collection PubMed
description The title compound C(7)H(11)NO(3) was prepared by intra­molecular nucleophilic displacement of 2,3-O-iso-propyl­idene-d-erythronolactol. There are two mol­ecules in the asymmetric unit, which are related by a pseudo-inversion centre. The crystal structure determination confirms unequivocally the configuration of the chiral centres as 3S,4R. In the crystal structure, inter­molecular C—H⋯O inter­actions link the mol­ecules (into infinite zigzag chains along the a axis.
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spelling pubmed-30893702011-07-13 (3R,4S)-3,4-Isopropyl­idenedioxy-3,4-dihydro-2H-pyrrole 1-oxide Flores, Mari Fe Garcia, Pilar M. Garrido, Narciso Sanz, Francisca Diez, David Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound C(7)H(11)NO(3) was prepared by intra­molecular nucleophilic displacement of 2,3-O-iso-propyl­idene-d-erythronolactol. There are two mol­ecules in the asymmetric unit, which are related by a pseudo-inversion centre. The crystal structure determination confirms unequivocally the configuration of the chiral centres as 3S,4R. In the crystal structure, inter­molecular C—H⋯O inter­actions link the mol­ecules (into infinite zigzag chains along the a axis. International Union of Crystallography 2011-04-13 /pmc/articles/PMC3089370/ /pubmed/21754432 http://dx.doi.org/10.1107/S1600536811013055 Text en © Flores et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Flores, Mari Fe
Garcia, Pilar
M. Garrido, Narciso
Sanz, Francisca
Diez, David
(3R,4S)-3,4-Isopropyl­idenedioxy-3,4-dihydro-2H-pyrrole 1-oxide
title (3R,4S)-3,4-Isopropyl­idenedioxy-3,4-dihydro-2H-pyrrole 1-oxide
title_full (3R,4S)-3,4-Isopropyl­idenedioxy-3,4-dihydro-2H-pyrrole 1-oxide
title_fullStr (3R,4S)-3,4-Isopropyl­idenedioxy-3,4-dihydro-2H-pyrrole 1-oxide
title_full_unstemmed (3R,4S)-3,4-Isopropyl­idenedioxy-3,4-dihydro-2H-pyrrole 1-oxide
title_short (3R,4S)-3,4-Isopropyl­idenedioxy-3,4-dihydro-2H-pyrrole 1-oxide
title_sort (3r,4s)-3,4-isopropyl­idenedioxy-3,4-dihydro-2h-pyrrole 1-oxide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3089370/
https://www.ncbi.nlm.nih.gov/pubmed/21754432
http://dx.doi.org/10.1107/S1600536811013055
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