Aqua­bromidobis(dimethyl­glyoximato)cobalt(III)

In the title complex, [CoBr(C(4)H(7)N(2)O(2))(2)(H(2)O)], a crystallo­graphic mirror plane bis­ects the mol­ecule, perpendicular to the glyoximate ligands. The geometry around the cobalt(III) atom is approximately octa­hedral with the four glyoximate N atoms forming the square base. A bromide ion and the O atom of a water mol­ecule occupy the remaining coordination sites. The N—Co—N bite angles are 82.18 (4) and 80.03 (16)°. The glyoximate moieties form strong intra­molecular O—H⋯O hydrogen bonds. The coordinated water mol­ecule forms an inter­molecular O—H⋯O hydrogen bond with a glyoximate O atom, thereby generating supra­molecular chains parallel to [010].