Poly[bis­(μ(2)-3-carb­oxy­benzoato)bis­(dipyrido[3,2-a;2′,3′-c]phenazine)bis­(μ(3)-isophthalato)tricopper(II)]

In the title compound, [Cu(3)(C(8)H(4)O(4))(2)(C(8)H(5)O(4))(2)(C(18)H(10)N(4))(2)](n), one Cu(II) atom, located on an inversion center, is hexa­coordinated and shows a distorted octa­hedral coordination geometry, while the other Cu(II) atom is penta­coordinated and exhibits a distorted square-pyram...

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Detalles Bibliográficos
Autor principal: Wang, Xiao-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099755/
https://www.ncbi.nlm.nih.gov/pubmed/21753967
http://dx.doi.org/10.1107/S1600536811008993
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author Wang, Xiao-Fang
author_facet Wang, Xiao-Fang
author_sort Wang, Xiao-Fang
collection PubMed
description In the title compound, [Cu(3)(C(8)H(4)O(4))(2)(C(8)H(5)O(4))(2)(C(18)H(10)N(4))(2)](n), one Cu(II) atom, located on an inversion center, is hexa­coordinated and shows a distorted octa­hedral coordination geometry, while the other Cu(II) atom is penta­coordinated and exhibits a distorted square-pyramidal geometry. The Cu(II) atoms are bridged by isophthalate and 3-carb­oxy­benzoate ligands, forming a chain structure along the b axis. Furthermore, the chains are linked by O—H⋯O hydrogen bonds, forming a layer parallel to the ab plane.
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spelling pubmed-30997552011-07-13 Poly[bis­(μ(2)-3-carb­oxy­benzoato)bis­(dipyrido[3,2-a;2′,3′-c]phenazine)bis­(μ(3)-isophthalato)tricopper(II)] Wang, Xiao-Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(3)(C(8)H(4)O(4))(2)(C(8)H(5)O(4))(2)(C(18)H(10)N(4))(2)](n), one Cu(II) atom, located on an inversion center, is hexa­coordinated and shows a distorted octa­hedral coordination geometry, while the other Cu(II) atom is penta­coordinated and exhibits a distorted square-pyramidal geometry. The Cu(II) atoms are bridged by isophthalate and 3-carb­oxy­benzoate ligands, forming a chain structure along the b axis. Furthermore, the chains are linked by O—H⋯O hydrogen bonds, forming a layer parallel to the ab plane. International Union of Crystallography 2011-03-15 /pmc/articles/PMC3099755/ /pubmed/21753967 http://dx.doi.org/10.1107/S1600536811008993 Text en © Xiao-Fang Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Xiao-Fang
Poly[bis­(μ(2)-3-carb­oxy­benzoato)bis­(dipyrido[3,2-a;2′,3′-c]phenazine)bis­(μ(3)-isophthalato)tricopper(II)]
title Poly[bis­(μ(2)-3-carb­oxy­benzoato)bis­(dipyrido[3,2-a;2′,3′-c]phenazine)bis­(μ(3)-isophthalato)tricopper(II)]
title_full Poly[bis­(μ(2)-3-carb­oxy­benzoato)bis­(dipyrido[3,2-a;2′,3′-c]phenazine)bis­(μ(3)-isophthalato)tricopper(II)]
title_fullStr Poly[bis­(μ(2)-3-carb­oxy­benzoato)bis­(dipyrido[3,2-a;2′,3′-c]phenazine)bis­(μ(3)-isophthalato)tricopper(II)]
title_full_unstemmed Poly[bis­(μ(2)-3-carb­oxy­benzoato)bis­(dipyrido[3,2-a;2′,3′-c]phenazine)bis­(μ(3)-isophthalato)tricopper(II)]
title_short Poly[bis­(μ(2)-3-carb­oxy­benzoato)bis­(dipyrido[3,2-a;2′,3′-c]phenazine)bis­(μ(3)-isophthalato)tricopper(II)]
title_sort poly[bis­(μ(2)-3-carb­oxy­benzoato)bis­(dipyrido[3,2-a;2′,3′-c]phenazine)bis­(μ(3)-isophthalato)tricopper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099755/
https://www.ncbi.nlm.nih.gov/pubmed/21753967
http://dx.doi.org/10.1107/S1600536811008993
work_keys_str_mv AT wangxiaofang polybism23carboxybenzoatobisdipyrido32a23cphenazinebism3isophthalatotricopperii

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